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Nanoscale origins of super-capacitance phenomena
(2019-02-28)
We review the origins of capacitive phenomena at the nanoscale to demonstrate that electrochemistry cannot be understood without a critical re-reading of nanoscale electronics, and vice-versa. The fundamentals are stated ...
Electrochemistry and STM-assisted Molecular electronics study of bimetallic hexaphyrins
(Universidade Federal de São CarlosUFSCarPrograma de Pós-Graduação em Química - PPGQCâmpus São Carlos, 2019-09-23)
ELECTROCHEMISTRY AND STM-ASSISTED MOLECULAR ELECTRONICS STUDY OF BIMETALLIC HEXAPHYRINS. The electron transport in porphyrinoids are related to several bioprocesses in Nature, from conversion from solar energy to chemical ...
Magnetic MIPs: Synthesis and Applications
(2021-01-01)
Magnetic molecularly imprinted polymers (MMIPs) are constructed based on the blending of inorganic nanoparticles with molecularly imprinted polymers (MIPs). MMIPs are synthesized in a core-shell format in which inorganic ...
Common Principles of Molecular Electronics and Nanoscale Electrochemistry
(Amer Chemical Soc, 2018-06-19)
The merging of nanoscale electronics and electrochemistry can potentially modernize the way electronic devices are currently engineered or constructed. This Feature offers a conceptual discussion of this central topic, ...
Electrochemistry and first principles of quantum mechanics
(2018-01-01)
In Chap. 1, we demonstrated that nanoscale electronics and electrochemistry both originate from the same physical background and are underpinned by chemical capacitance and its association with quantised relaxation resistance, ...
Probing the electronic delocalization in a cyclic pyrazine ruthenium cluster hexamer
(ELSEVIER SCIENCE BV, 2010)
[Ru(3)O(CH(3)COO)(6)(pz)(CO)](6) is a cyclic hexamer species encompassing six triangular ruthenium cluster centers bridged by pyrazine ligands. The electronic communication among the cluster units strongly depends on their ...
Field effect in molecule-gated switches and the role of target-to-receptor size ratio in biosensor sensitivity
(2019-02-15)
We demonstrated here that molecular redox films are electrochemical capacitive devices possessing specific field effect in which molecular moieties within films act as sensitive gates. We confirm that the field effect ...