wo new mixed-metal mixed-valent complexes, of formulae: [(CO)3(bpy)ReI(bpe)RuIII(NH3)5]4+ and [(CO)3(bpy)ReI(4-CNpy)RuIII(NH3)5]4+ (where bpy=2,2′-bipyridine, bpe=trans-1,2-bis(4-pyridil)ethene, 4-CNpy=4-cyanopyridine), ...

We report the first example of a polynuclear discrete coordination compound exhibiting only bpym bridges and containing a first-row d transition metal. A smooth self-assembly one-pot synthetic route, starting from simply ...

Two porous mixed valent diruthenium(II,III)-dicarboxylate compounds have been prepared and characterized by spectroscopic methods, X-ray diffraction and thermogravimetry. Crystalline solids of [Ru(2)(tere)(2)Cl] center dot ...

Two novel mixed-valent ruthenium complexes, of formulae [(tpy)(bpy)RuII(pz)RuIII(edta)]+ and [(CN)4RuII(bpz)RuIII(edta)]3- (where tpy = 2,2′:6′,2″-terpyridine, bpy = 2,2′-bipyridine, pz = pyrazine, bpz = 2,2′-bipyrazine, ...

We are reporting two new mixed valent Co(ii)/Co(iii) polynuclear complexes, {Co II 6 Co III 3 } and {Co II Co III 4 }, bearing different amount of Co(ii) ions in their cores, through the employment of the multidentate ...

We report on a convergent approach for the generation of dendrimers containing the [Ru3O(aC)(6)] electroactive core, of great interest as multielectron transfer catalysts. The proposed strategy is based on the generation ...

The preparation and characterization by spectroscopic and electrochemical techniques of new dinuclear complexes of the type [(tpm)(bpy)RuII(L)RuII/III(NH3)5]4+/5+ (bpy =2,2'-bipyridine, tpm = tris(1-pyrazolyl)methane, L = ...