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Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde
(Elsevier Inc., 2018-10)
Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K. The reaction was carried out in batch ...
Phase equilibria in ternary mixtures of methyl oleate, glycerol, and methanol
(American Chemical Society, 2008-08)
Transesterification reactions are common in the production of some important chemicals, such as biodiesel and mono- and diglycerides. Knowledge of the phase equilibrium conditions of the reactive mixture is essential to ...
Self-metathesis of methyl oleate on silica-supported Hoveyda-Grubbs catalysts
(Elsevier, 2013-08)
The self-metathesis of methyl oleate (MO) to yield 9-octadecene and 9-octadecene-1,18-dioate (9-OD) was studied in liquid-phase on silica-supported Hoveyda–Grubbs complex catalysts (HG/SiO2) containing 0.43–6.0 wt.% HG. ...
Liquid-liquid equilibria in ternary mixtures of methyl oleate + ethanol + glycerol at atmospheric pressure
(American Chemical Society, 2012)
Efficient production of biodiesel from low-cost feedstock using zinc oleate as catalyst
(Elsevier Science, 2015-03-21)
In this study, the synthesis of fatty acid methyl esters (FAME) by the transesterification of low-cost feedstock containing 10 and 22 wt.% free fatty acid (FFA), using zinc oleate (ZnOl) as catalyst, was investigated. The ...
Biocatalytic benefits of immobilized Fusarium sp. (GFC) lipase from solid state fermentation on free lipase from submerged fermentation
(2020-05-01)
Lipases are promising tools for the synthesis of high value-added compounds and have traditionally been obtained from submerged fermentation processes (SmF). However, solid-state fermentation (SSF) allows linking the ...
Heterogeneous catalysis for valorisation of vegetable oils via metathesis reactions: Ethenolysis of methyl oleate
(Royal Society of Chemestry, 2016-06)
The cross-metathesis of methyl oleate (MO) with ethylene was studied on a second-generation Hoveyda?Grubbs complex supported on silica (HG/SiO2). The reaction was carried out in a batch slurry reactor at 313?353 K and ...
Valorisation of plant oil derivatives via metathesis reactions: study of the cross-metathesis of methyl oleate with cinnamaldehyde
(Elsevier, 2020-02)
The cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) to yield 2-undecenal, methyl 11-oxo-9-undecenoate, methyl 10-phenyl-9-decenoate and 1-decenylbenzene was investigated using the second-generation ...
Methyl Oleate Isomerization and Hydrogenation over Ni/α-Al2O3: A Kinetic Study Recognizing Differences in the Molecular Size of Hydrogen and Organic Species
(Elsevier Science, 2008-02)
The kinetics of the hydrogenation and cis/trans isomerization of methyl oleate on a Ni/a-Al2O3 catalyst was studied in the absence of mass-transport limitation, at 398K=T=443Kand370kPa = PH2 = 650 kPa. On the basis of the ...