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Matrix isolation studies of carbonyl selenide, OCSe: Evidence of the formation of dimeric species, (OCSe)2
(Elsevier Science, 2014-01)
OCSe isolated in solid Ar or N2 at 10 K was investigated by FTIR spectroscopy. The IR spectra of OCSe diluted in a 1:1000 proportion with the matrix gases were interpreted in terms of monomeric carbonyl selenide in a single ...
Hydrophilic Isolates of Rye Flour as a Potential Matrix for the Use as a Vehicle of Active Compounds
(MDPI, 2019-11)
The isolation of water-soluble polysaccharides and proteins solubilized during the treatment of rye flour in an isotonic aqueous medium is described. Protein and polysaccharide assays of the aqueous fractions showed the ...
Matrix isolation of the elusive fluorocarbonylsulfenyl fluoride molecule FC(O)SF
(American Chemical Society, 2013-02-25)
The syn and anti conformers of the hitherto unknown fluorocarbonylsulphenyl fluoride, FC(O)SF, were formed through the photochemical reactions between OCS and F2 , isolated in solid Ar. The reactions were followed by FTIR ...
UV-induced photochemistry of matrix-isolated 1-phenyl-4-allyl-tetrazolone
(Royal Society of Chemistry, 2007-12)
The photochemistry and molecular structure of 1-phenyl-4-allyl-tetrazolone (PAT) was studied by FT-IR matrix isolation spectroscopy and DFT(B3LYP)/6-311++G(d,p) calculations. The spectrum of matrix-isolated PAT monomers ...
Conformational and structural analysis of 2-allyl-1,2-benzisothiazol-3(2H)-one 1,1-dioxide as probed by matrix-isolation spectroscopy and quantum chemical calculations
(Elsevier Science, 2009-02)
2-Allyl-1,2-benzisothiazol-3(2H)-one 1,1-dioxide (ABIOD) has been studied by matrix-isolation infrared spectroscopy and quantum chemical calculations. A conformational search on the B3LYP/6-311++G(3df,3pd) potential energy ...
Matrix Isolation Study of the Conformations and Photochemistry of S‑Ethyl Fluorothioformate, FC(O)SCH2CH3
(American Chemical Society, 2014-11-03)
The IR spectra of S-ethyl fluorothioformate, FC(O)SCH2CH3, were recorded in the vapor phase and compared with the Raman spectrum in the liquid state. Additional IR spectra of the compound isolated in argon and nitrogen ...
Gas-phase and matrix-isolation photochemistry of methyl thioglycolate, CH 3 OC(O)CH 2 SH: Influence of the presence of molecular oxygen in the photochemical mechanisms
(Elsevier Science Sa, 2017-07)
The photochemistry of methyl thioglycolate (MTG), CH3OC(O)CH2SH, in gas phase and in matrix isolation conditions was studied by means of FTIR spectroscopy, and the influence of the presence of molecular oxygen on the ...
Conformers, infrared spectrum, UV-induced photochemistry, and near-IR-induced generation of two rare conformers of matrix-isolated phenylglycine
(American Institute of Physics, 2014-10)
The conformational space of α-phenylglycine (PG) have been investigated theoretically at both the DFT/B3LYP/6-311++G(d,p) and MP2/6-311++G(d,p) levels of approximation. Seventeen different minima were found on the investigated ...
Self-aggregation in pyrrole: Matrix isolation, solid state infrared spectroscopy, and DFT study
(American Chemical Society, 2004-08)
Pyrrole (C4H5N) was embedded in low-temperature solid inert matrixes (argon, xenon; T = 9 K.) and both the monomer and low-order aggregates characterized by FTIR spectroscopy. The spectroscopic studies were complemented ...