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Role of aluminum chloride on the reversible hydrogen storage properties of the Li-N-H system
(Pergamon-Elsevier Science Ltd, 2015-10)
In order to understand the role of AlCl3 addition on the Li-N-H system, we have systematically investigated the hydrogen sorption kinetics and the reactions between LiNH2-LiH and AlCl3 additive with a multitechnique approach ...
Hydrogen storage properties of LiNH2-LiH system with MgH2, CaH2 and TiH2 added
(Pergamon-Elsevier Science Ltd, 2015-08-10)
The addition of different metal hydrides to Li–N–H system offers a possible way to modify its thermodynamic properties and/or the dehydrogenation/hydrogenation kinetics. In this paper we report the hydrogen storage properties ...
Destabilization of the LiNH2–LiH hydrogen storage system by aluminum incorporation
(Elsevier, 2013-09)
The lithium amide–lithium hydride system (LiNH2–LiH) is one of the most attractive light-weight materials for hydrogen storage. In an effort to improve its hydrogen sorption kinetics, the effect of 1 mol% AlCl3 addition ...
Monomeric Germanium(II) Amides Bearing β-Diketiminato Ligands: Synthesis, Structural Characterization, and Thermal Properties
(2014-09)
Germanium(II) compounds featuring β-diketiminate-type ligands are attractive for applications as nanoparticle precursors, imaging agents, and components of electronic devices. In this work, we report the synthesis of ...
Monomeric Germanium(II) Amides Bearing β-Diketiminato Ligands: Synthesis, Structural Characterization, and Thermal Properties
(2014-09)
Germanium(II) compounds featuring β-diketiminate-type ligands are attractive for applications as nanoparticle precursors, imaging agents, and components of electronic devices. In this work, we report the synthesis of ...
A wide mechanistic spectrum observed in three different reactions with organometallic reagents
(John Wiley & Sons Ltd, 2010-10)
The halogen-lithium exchange reaction is of one of the most powerful method for the preparation of organolithium compounds, but its mechanism is still controversial. To afford some new elements, we synthesized a new suitable ...
Clarifying the dehydrogenation pathway of catalysed Li4(NH2)3BH4-LiH composite
(Royal Society of Chemistry, 2017-12-15)
The effect of different metal oxides (Co3O4 and NiO) on the dehydrogenation reactions pathways of the Li4(NH2)3BH4-LiH composite was investigated. The additives were reduced to metallic species i.e. Co and Ni which act as ...
Effective participation of Li4(NH2)3BH4 in the dehydrogenation pathway of the Mg(NH2)2-2LiH composite
(Royal Society of Chemistry, 2016-06)
Lithium fast-ion conductors have shown positive effects on the hydrogen storage properties of the Li-Mg-N-H system. In the present work, Li4(NH2)3BH4 doped Mg(NH2)2-2LiH was formed by milling the 2LiNH2-MgH2-0.2LiBH4 ...
Preparación, estudio y optimización de amiduros de litio y magnesio para almacenamiento de hidrógenoPreparation, study and optimization of lithium and magnesium amidides for hydrogen storage
(2018-09-27)
El desarrollo de esta Tesis de Doctorado en Ciencias de la Ingeniería se centró en el estudio de materiales compuestos para almacenamiento de hidrógeno basado en amiduros, tanto de litio como de magnesio, con propiedades ...