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Syntheses and characterization of binuclear Rh-2, Ir-2 and RhIr complexes containing dimethyl phosphonate and pyrazolate bridging ligands
(ROYAL SOC CHEMISTRY, 1996)
The reaction of [Ir(eta(5)-C(5)Me(5))I{PO(OMe)(2)}{P(OH)OMe)(2)}] with pyrazole (Hpz) in the presence of AgPF6 gave [Ir(eta(5)-C(5)Me(5)){PO(OMe)(2)}{P(OH)(OMe)(2)}(Hpz)]PF6 1. Deprotonation of 1 with sodium carbonate ...
Two-photon absorption properties and 1 O 2 generation ability of Ir complexes: an unexpected large cross section of [Ir(CO) 2 Cl(4-(para-di-n-butylaminostyryl)pyridine)]
(Royal Society of Chemistry, 2015-07)
The new complexes cis-[Ir(CO)2Cl(4-(para-di-n-butylaminostyryl)pyridine)] (1) and [Ir(cyclometallated-2-phenylpyridine)2(4,4′-(para-di-n-butylaminostyryl)-2,2′-bipyridine)][PF6] (3) were synthesized and fully characterized ...
Synthesis and structure of some heterobimetallic complexes having a polyalkyl-s-indacenyl spacer
(ELSEVIER SCIENCE SA, 2013)
Three heterobimetallic complexes LmM(s-Ic')M'Ln (M = Fe, Ru or Mn; M' = Ni) having the same Cp* nickel moiety and based on a polyalkyl-s-indacenyl spacer (s-Ic' = 2,6-diethyl-4,8-dimethyl-s-indacenyl) were synthesized by ...
Electrochemical triggered O-atom transfer reaction in nitrocarbonyl rhenium(I) complexes: An IR spectroelectrochemical investigation
(Elsevier, 2015-07-11)
In previous work we proposed that polypyridylrhenium(I)tricarbonyl complexes coordinated to ion nitrite through its N-atom in CH2Cl2 solution could give nitrosyl complexes by electrochemical oxidation. In this work, we ...
The effect of guest molecules on the conformation and molecular assembly of the fac-[RuCl3(NO)(dppb)] complex
(Elsevier BVAmsterdam, 2013-09)
This paper describes the occurrence of two crystalline solvate forms of the nitrosyl ruthenium complex fac-[RuCl3(NO)(dppb)] (dppb = 1,4-bis(diphenylphosphino)butane), and the role of acetone and chloroform inclusions on ...
New Rh derivatives of s-indacene active in dehydrogenative silylation of styrene
(ELSEVIER SCIENCE SA, 2006)
The mono- and bimetallic complexes [(2,6-diethyl-4,8-dimethyl-s-indacenide){Rh(COD)}] (1), anti-[(2,6-diethyl-4,8-dimethyl-s-indacenediide) {Rh(COD)}(2)] (2a), syn-[(2,6-diethyl-4,8-dimethyl-s-indacenediide){Rh(COD)}(2)] ...
Thermal decomposition of palladium(II) pyrazolyl complexes. Part I
(Elsevier B.V., 2004-08-01)
The thermal behavior of simple and mixed pyrazolyl complexes [PdCl2(phmPz)(2)] (1),[Pd(N-3)(2)(phmPz)(2)] (2), [Pd(SCN)(2)(phmPz)(2)] (3), and [Pd(N-3)(SCN)(phmPz)(2)] (4) (phmPz: 1-phenyl-3-methylpyrazole) has been ...
Thermal decomposition of palladium(II) pyrazolyl complexes. Part I
(Elsevier B.V., 2004-08-01)
The thermal behavior of simple and mixed pyrazolyl complexes [PdCl2(phmPz)(2)] (1),[Pd(N-3)(2)(phmPz)(2)] (2), [Pd(SCN)(2)(phmPz)(2)] (3), and [Pd(N-3)(SCN)(phmPz)(2)] (4) (phmPz: 1-phenyl-3-methylpyrazole) has been ...