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Interference-free calibration with first-order instrumental data and multivariate curve resolution: when and why?
(Elsevier Science, 2021-05)
The possibility of building an interference-free calibration with first-order instrumental data with multivariate curve resolution-alternating least-squares (MCR-ALS) has been a recent topic of interest. When the protocols ...
Direct determination of trans-resveratrol in human plasma by spectrofluorimetry and second-order standard addition
(Elsevier Science BvAmsterdamHolanda, 2010)
Analysis of citrulline and metabolic related amino acids in plasma by derivatization and RPLC. Application of the extrapolative internal standard calibration method
(Elsevier Science, 2016-11)
We propose to apply the extrapolative internal standard calibration method (EISM) for quantitative analysis of citrulline and other metabolically related amino acids in plasma by pre-columnderivatization, liquid chromatography ...
Study of matrix effects and spectral interferences in the determination of lead in sediments, sludges and soils by SR-ETAAS using slurry sampling
(Elsevier Science, 2010-07)
An interference-free, fast, and simple method is proposed for Pb determination in environmental solid samples combining slurry sampling and electrothermal atomic absorption spectrometry. Samples were ground to an adequate ...
Determination of free and total glycerol in biodiesel by spot analysis
(Elsevier Science, 2020-11)
The importance of alternative fuel production has increased in the lately years, and so has the need of methods of analysis to evaluate their quality. Biodiesel fuel is a valuable substitute to petrodiesel fuel. Among the ...
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
(Elsevier, 2013-04)
This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol ...
Combination of electrochemistry with chemometrics to introduce an efficient analytical method for simultaneous quantification of five opium alkaloids in complex matrices
(Elsevier, 2015-01)
For the first time, an analytical methodology based on differential pulse voltammetry (DPV) at a glassy carbon electrode (GCE) and integration of three efficient strategies including variable selection based on ant colony ...
Potencialidades das técnicas com fonte de plasma e da espectrometria de absorção atômica em forno de grafite de alta resolução com fonte contínua para análise de fertilizantes
(Universidade Federal de São CarlosUFSCarPrograma de Pós-Graduação em Química - PPGQCâmpus São Carlos, 2018-04-26)
Each year, Brazil sets records on agricultural productivity, which significantly increases the use of fertilizers in crops to provide the essential nutrientes. However, fertilizers can also be sources of toxic elements ...
Aspectos analíticos em TS-FF-AAS: estudo de interferências e aplicação para a determinação de metais em vinhos e sucos
(Universidade Federal de São CarlosBRUFSCarPrograma de Pós-Graduação em Química - PPGQ, 2007-02-28)
In this work, it was evaluated the effects of interferences caused by major and minor constituents on Co, Cu and Mn atomized by flame atomic absorption spectrometry (FAAS) and by thermospray flame furnace atomic absorption ...
Advanced and tailored applications of an efficient electrochemical approach assisted by AsLSSRCOW- rPLS and finding ways to cope with challenges arising from the nature of voltammetric data
(Elsevier, 2015-07)
The use of chemometric data processing is becoming an important part of modern voltammetry. The most challenges arising from voltammetric data are interactions among analytes and the background interferents which may cause ...