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Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias
(Editora Unesp, 1997-01-01)
Reactions of [WC1(CO)(3)(bipy)(HgCl)], [bipy = 2,2 -bipyridine], with thioureas were performed giving compounds of the type [WCl(CO)(3)(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethyithiourea (dmtu)] ...
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias
(Editora Unesp, 1997-01-01)
Reactions of [WC1(CO)(3)(bipy)(HgCl)], [bipy = 2,2 -bipyridine], with thioureas were performed giving compounds of the type [WCl(CO)(3)(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethyithiourea (dmtu)] ...
Design of 3d-4f molecular squares through the [Fe{(HB(pz)3)}(CN)3]- metalloligand
(Universidade Federal de Minas GeraisBrasilICX - DEPARTAMENTO DE QUÍMICAUFMG, 2018)
Reactivity of towards copper (I) compounds: Synthesis of binuclear heteromettalic species having CS2 bridging Fe(O) and Cu(I)Reatividade do [Fe(CO)2(2-CS2)(PPh3)2] frente a compostos de Cu(I): Síntese de espécies binucleares heterometálicas contendo CS2 em ponte entre Fe(0) e Cu(I).
(2007-01-01)
This work describes the one pot syntheses and characterization of two new heterometallic carbonyl compounds of the type [Fe(CO)3(m-CS2)(PPh3)(CuX)], X = Cl, ClO4. Both compounds were investigated by infrared and 31P{1H} ...
σ-Aromaticity-Induced Stabilization of Heterometallic Supertetrahedral Clusters [Zn6Ge16]4− and [Cd6Ge16]4−
(2020-09-21)
In this work, the largest heterometallic supertetrahedral clusters, [Zn6Ge16]4− and [Cd6Ge16]4−, were directly self-assembled through highly-charged [Ge4]4− units and transition metal cations, in which 3-center–2-electron ...
Cu(II)–Gd(III) 2D-coordination polymer based on two different organic linkers
(Elsevier, 2017)
A new CuII–GdIII heterometallic coordination polymer was obtained by a two-step synthesis, using the
molecular complex [Cu(H2IDC)2(2,20-bipy)] 2H2O (1) as metalloligand and oxalate as auxiliary ligand
(H3IDC = ...
Molybdenum Induces the Expression of a Protein Containing a New Heterometallic Mo-Fe Cluster in Desulfovibrio alaskensis
(American Chemical Society, 2009-02)
The characterization of a novel Mo-Fe protein (MorP) associated with a system that responds to Mo in Desulfovibrio alaskensis is reported. Biochemical characterization shows that MorP is a periplasmic homomultimer of high ...