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Synthesis of 5-deoxy-β-d-galactofuranosides as tools for the characterization of β-d-galactofuranosidases
(Pergamon-Elsevier Science Ltd, 2010-07)
Derivatives of 5-deoxy-β-d-galactofuranose (5-deoxy-α-l-arabino- hexofuranose) have been synthesized starting from d-galacturonic acid. The synthesis of methyl 5-deoxy-α-l-arabino-hexofuranoside (14α) was achieved by an ...
Synthesis of the (1→6)-linked thiodisaccharide of galactofuranose. Inhibitory activity against a β-galactofuranosidase
(Elsevier, 2013-06-01)
Methyl (methyl alpha,beta-D-galactofuranosid)uronate was employed as the starting compound,which was per-O-silylated with TBSCl and reduced with LiAlH4 to afford methyl 2,3,5-tri-O-tert-butyldimethylsilyl-b-D-galactofuranoside ...
Estudios de glicosidación 1, 2-cis con donores conformacionalmente restringidos 3,5-O-di-ter-butilsililén-D-galactofuranósidosGlycosylation studies 1,2-cis on conformationally restricted 3,5-O-DI-tert-butylsilylene-D-Galactofuranoside donors
(Facultad de Ciencias Exactas y Naturales. Universidad de Buenos Aires, 2012)
Estudios de glicosidación para la obtención estereoselectiva de alfa-D-galactofuranósidos 1,2-cis. Aplicación a la síntesis del trisacárido constituyente del polisacárido capsular de Streptococcus pneumoniae 22 F}Glycosylation studies for the stereoselective synthesis of alfa-D-galactofuranosides 1,2-cis. Application to the synthesis of the trisaccharide constituent of Streptococcus pneumoniae 22f capsular polysaccharide
(Facultad de Ciencias Exactas y Naturales. Universidad de Buenos Aires, 2013)
Synthesis of alpha-D-Glcp-(1-3)-alpha-D-Galf-(1-2)-alpha-L-Rhap constituent of the CPS of Streptococcus pneumoniae 22F. Effect of 3-O-substitution in 1,2-cis alpha-D-galactofuranosylation
(Royal Society of Chemistry, 2014-01)
The synthesis of the trisaccharide a-D-Glcp-(1-3)-a-D-Galf-(1-2)-L-Rhap (3) constituent of Streptococcus pneumonia 22F was achieved with complete diastereoselectively. This is the first example of a synthesis of an internal ...