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The Influence of Mn(II) and Aging Time in the Ferrihydrite to Goethite Transformation
(Bentham Science Publishers, 2008-12)
The ferrihydrite-goethite transformation in samples of pure- and Mn-ferrihydrite was investigated in order to elucidate the effect of Mn(II) in the aging process. Samples of pure- and Mn-ferrihydrites were aged for different ...
Boron adsorption to ferrihydrite with implications for surface speciation in soils: Experiments and modeling
(2020-07-29)
The adsorption and desorption of boric acid onto reactive materials such as metal (hydr)oxides and natural organic matter are generally considered to be controlling processes for the leaching and bioavailability of boron ...
Magnetic characterization of ferrihydrite nanoparticles synthesized by hydrolysis of Fe metal-organic precursor
(ELSEVIER SCIENCE BV, 2008)
We investigate the formation of ferrihydrite nanoparticles (NPs) by hydrolysis of the Fe(III) alkoxide Fe(O(t)Bu)(3). Controlled amounts of water, up to 3.0 vol%, were added to the precursor solution yielding a series of ...
Evolution of the reactive surface area of ferrihydrite: time, pH, and temperature dependency of growth by Ostwald ripening
(2019-02)
Surface area is a crucial property of metal oxides for scaling ion adsorption phenomena. For ferrihydrite (Fh), the value is uncertain. Moreover, it rapidly changes with time, pH, and temperature. In this study, the dynamic ...
Assessing the reactive surface area of soils and the association of soil organic carbon with natural oxide nanoparticles using ferrihydrite as proxy
(2020-09-09)
Assessment of the surface reactivity of natural metal-(hydr)oxide nanoparticles is necessary for predicting ion adsorption phenomena in soils using surface complexation modeling. Here, we describe how the equilibrium ...
Carbonate adsorption to ferrihydrite: Competitive interaction with phosphate for use in soil systems
(2018-12)
Carbonate (CO3) interacts with Fe-(hydr)oxide nanoparticles, affecting the availability and geochemical cycle of other important oxyanions in nature. Here, we studied the carbonate–phosphate interaction in closed systems ...
Bacteria encapsulation in a magnetic sol-gel matrix
(Royal Society of Chemistry, 2009-01)
The encapsulation of Escherichia coli bacteria within ferrihydrite gels favours the long-term viability of the entrapped cells while preserving the magnetic properties of the host material.
Nanocomposites materials generated from a spray
(Sociedade Brasileira de Física, 2009-04-01)
The Spray Pyrolysis (SP) process has been employed at moderate temperature (470-970 K) for the synthesis of micro- and nano-particles of hydrated metal oxides and of related nanocomposites. It has been applied to iron ...
Nanocomposites materials generated from a spray
(Sociedade Brasileira de Física, 2009-04-01)
The Spray Pyrolysis (SP) process has been employed at moderate temperature (470-970 K) for the synthesis of micro- and nano-particles of hydrated metal oxides and of related nanocomposites. It has been applied to iron ...
Laboratory synthesis of goethite and ferrihydrite of controlled particle sizes
(Universidad Nacional Autónoma de México, Instituto de Geología, 2015)