We present the derivation of a general mathematical model for facilitated proton transfer (FPT) reactions across a liquid|liquid (L|L) interface assisted by a protonatable neutral weak base at a thick organic film modified ...

The theory of cyclic voltammetry of facilitated proton transfer-electron transfer coupled reactions (FPT-ET reactions) in a thick organic film modified electrode is developed. It is shown that the coupling between the ...

The theory of cyclic voltammetry of ion transfer-electron transfer coupled reactions in a thick organic film modified electrode is developed. The model system consists of a planar electrode completely covered by an organic ...

The mechanism of a simple S N2 reaction, viz; OH - + CH 3F = CH 3OH + F - has been studied within the framework of reaction force and reaction electronic flux. We have computationally investigated three different types of ...

The reaction mechanism of the hemiacetal formation from formaldehyde and methanol has been studied theoretically at the B3LYP/6-311+ +G(d,p) level. In addition to the study of the reaction between the isolated reactants, ...

The main purpose of the current work is to generalize the analytical model for the facilitated proton transfer-electron transfer coupled reactions at thick organic film-modified electrodes, including ion pairing in the ...

Studying chemical reactions involves the knowledge of the reaction mechanism. Despite activation barriers describing the kinetics or reaction energies reflecting thermodynamic aspects, identifying the underlying physics ...