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Theoretical model of ion transfer-electron transfer coupled reactions at the thick-film modified electrodes
(Elsevier Science Sa, 2017-01)
The theory of cyclic voltammetry of ion transfer-electron transfer coupled reactions in a thick organic film modified electrode is developed. The model system consists of a planar electrode completely covered by an organic ...
Facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2017-12)
The theory of cyclic voltammetry of facilitated proton transfer-electron transfer coupled reactions (FPT-ET reactions) in a thick organic film modified electrode is developed. It is shown that the coupling between the ...
Facilitated proton transfer via water autoprotolysis-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2020-07)
We present the derivation of a general mathematical model for facilitated proton transfer (FPT) reactions across a liquid|liquid (L|L) interface assisted by a protonatable neutral weak base at a thick organic film modified ...
An integrated theoretical-experimental approach to understand facilitated proton transfer-electron transfer coupled reactions at thick-film modified electrodes
(Pergamon-Elsevier Science Ltd, 2018-09)
The main purpose of the current work is to generalize the analytical model for the facilitated proton transfer-electron transfer coupled reactions at thick organic film-modified electrodes, including ion pairing in the ...
Heterogeneous Photoinduced Homolytic Aromatic Substitution of Electron-Rich Arenes with Perfluoroalkyl Groups in Water and Aqueous Media ? A Radical-Ion Reaction
(Wiley VCH Verlag, 2013-02)
The photoinduced electron transfer (PET) substitution reaction of electron-rich aromatic nuclei with perfluoroalkyl Rf groups was carried out in water or aqueous mixtures to render substitution products resulting from ...
Characterization of the non-covalent docking motif in the isolated reactant complex of a double proton-coupled electron transfer reaction with cryogenic ion spectroscopy
(American Institute of Physics, 2020-06)
The solution kinetics of a proton-coupled electron transfer reaction involving two-electron oxidation of a Ru compound with concomitant transfer of two protons to a quinone derivative have been interpreted to indicate the ...
Reactions of halonorbornane and oxo-substituted derivatives with different anions by the electron transfer mechanism; redox catalysis in stabilized radicals
(Royal Society of Chemistry, 2010-09)
Reactions of 2-bromo-, 2-chloronorbornane, 3-chloronorbornan-2-one and 3-bromocamphor with Me3Sn-, Ph2P- or PhS- ions were studied by an SRN1 mechanism in liquid ammonia or DMSO. The results show that substrates having a ...
On the Electrochemical Deposition and Dissolution of Divalent Metal Ions
(Wiley-Blackwell, 2014-01-13)
The deposition of Cu2+ and Zn2+ from aqueous solution has been investigated by a combination of classical molecular dynamics, density functional theory, and a theory developed by the authors. For both cases, the reaction ...
A model for the effect of ion pairing on an outer sphere electron transfer
(Royal Society of Chemistry, 2020-05)
Ion pairing can strongly affect the rates of electron transfer reactions. To explain this effect we propose a model Hamiltonian which describes the interactions between the pairing ion and the reactant, solvent and inner ...