As soon as a liquid comes into contact with a solid, physicochemical reactions occur at the solid-liquid interface to form an electrical double layer. According to the classical theory, it is assumed that the laminar flow ...

The equilibrium properties of a charged plane immersed in an aqueous electrolyte solution are examined using a generalized Poisson–Boltzmann equation that takes into account the finite ion size by modeling the solution as ...

The differential capacitance is a fundamental property of an electrical double layer and thus important for the development of more efficient and environment-friendly energy storage devices. In addition to the bare ...

We propose a dynamical theory of how the chemical energy stored in a battery generates the electromotive force (emf). In this picture, the battery's half-cell acts as an engine, cyclically extracting work from its underlying ...

The differential capacitance of an electrical double layer is a topic of great importance to develop more efficient and environment-friendly energy storage devices: electric double layer supercapacitors. In addition to the ...

When a liquid is in contact with a solid, a physicochemical reaction occurs at the solid-liquid interface leading to the formation of the electric double layer. Whenever the mobile portion of this charge inside the liquid ...

Poisson-Boltzmann theory provides an established framework to calculate properties and free energies of an electric double layer, especially for simple geometries and interfaces that carry continuous charge densities. At ...

The differential capacitance of an electrical double layer is directly affected by properties of the electrolyte solution such as temperature, salt concentration, ionic size, and solvent structure. In the present work, we ...