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Doped deltahedral organo-Zintl superalkali cations
(Elsevier B.V., 2020-11-16)
The doped deltahedral Zintl clusters are known for decades. Here, we report a functionalized doped organo-Zintl clusters [Ge7P2R3](R = CH3, C2H5 & C3H3) derived from the doped [Ge7P2]2− Zintl ion by replacing germanium ...
[ge9{si(sime3)3}3{snph3}]: a tetrasubstituted and neutral deltahedral nine-atom cluster
(WILEY-V C H VERLAG GMBH, 2012)
[(me3si)si]3etge9pd(pph3), a pentafunctionalized deltahedral zintl cluster: synthesis, structure, and solution dynamics
(2016)
The title compound, which has a ten-atom deltahedral cluster core of Ge9Pd, was synthesized through insertion of Pd(PPh3) into the tetrasubstituted nona-germanium cluster [(Me3Si)Si](3)EtGe9 through a reaction of the latter ...
Eclipsed- and staggered-[ge18pd3{e'pr-3}(6)](2-) (e = si, sn): positional isomerism in deltahedral zintl clusters
(2017)
We report the synthesis and characterization of the cluster anions [Ge18Pd3{Si`Pr-3}(6)]2-(1) with a core of face fused twinned icosahedra, Ge18Pd3, and two sets of three 'Pr3Si-substituents positioned in "eclipsed" geometry. ...
Eclipsed- and Staggered-[Ge18Pd3{EiPr3}6]2- (E = Si, Sn): Positional Isomerism in Deltahedral Zintl Clusters
(American Chemical Society, 2017)