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Trithioorthoester Exchange and Metathesis: New Tools for Dynamic Covalent Chemistry
(Georg Thieme Verlag Kg, 2019-09)
To expand the toolbox of dynamic covalent and systems chemistry, we investigated the acid-catalyzed exchange reaction of trithioorthoesters with thiols. We found that trithioorthoester exchange occurs readily in various ...
Host Amplification in a Dithioacetal-Based Dynamic Covalent Library
(American Chemical Society, 2017-03)
Molecular amplification in a dithioacetal-based dynamic library is described for the first time. The homatropine induced selection, amplification, and isolation of one cyclophane host demonstrates the utility of dithioacetal ...
Chemical Frustration in Dynamic Multilevel Systems
(Natural & Life Science, 2020-10)
Dynamic multilevel systems constructed with sequential-communicating reactions are a poorly studied type of thermodynamic systems. Recent work of our group showed that multilevel sequential systems are history-dependent ...
Engineering multilayer chemical networks
(Royal Society of Chemistry, 2019-09)
Dynamic multilevel systems emerged in the last few years as new platforms to study thermodynamic systems. In this work, unprecedented fully communicated three-level systems are studied. First, different conditions were ...
Homodiselenacalix[4]arenes: Molecules with Unique Channelled Crystal Structures
(Wiley VCH Verlag, 2016-01)
A synthetic route towards homodiselenacalix[4]arene macrocycles is presented, based on the dynamic covalent chemistry of diselenides. The calixarene inner rim is decorated with either alkoxy or tert-butyl ester groups. ...
Chitosan-Acrylic Polymeric Nanoparticles with Dynamic Covalent Bonds. Synthesis and Stimuli Behavior
(Pharmaceutical Society of JapanBIOPOLIMERTokyo, Japón, 2023)
Molecular Networks in Dynamic Multilevel Systems
(Wiley VCH Verlag, 2018-09)
Dynamic multilevel systems can be assembled from molecular building blocks through two or more reversible reactions that form covalent bonds. Molecular networks of dynamic multilevel systems can exhibit different connectivities ...
Systematic process evaluation of the conjugation of proteins to gold nanoparticles
(Cell press, 2021)
The present work addresses some fundamental aspects in the preparation of protein-conjugated gold nanoparticles, in order to ensure an appropriate final product. Ten broadly available and/or easy to implement analytical ...
Importance of the electrolyte cation on the non-covalent interactions in the electrooxidation of 1-heptanol on gold in 0.1 M alkali metal hydroxides
(Elsevier, 2020)
In order to determine the possible non-covalent influence of the alkali metal cation on the electrooxidation of 1-heptanol on gold in alkali metal hydroxides, 0.1 M MOH solutions, where M = Li, Na, K, Rb, and Cs, have been ...
Benzoxaboroles as dynamic covalent receptors for bioconjugation and transport of nucleosides and related drugs: proof of action in HeLa cells
(Academic Press Inc Elsevier Science, 2019-06)
In this work we describe not previously explored binding studies on the reversible interaction of benzoxaborole with ligands of medical and pharmaceutical interest such as nucleosidic drugs gemcitabine and capecitabine, ...