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A química supramolecular de complexos pirazólicos
(Sociedade Brasileira de Química, 2008-01-01)
The purpose of this review is to describe the progress in the supramolecular chemistry of the pyrazolyl-based metal complexes. The text is written under the structural point of view, emphasizing the role of the covalent ...
A química supramolecular de complexos pirazólicos
(Sociedade Brasileira de Química, 2008-01-01)
The purpose of this review is to describe the progress in the supramolecular chemistry of the pyrazolyl-based metal complexes. The text is written under the structural point of view, emphasizing the role of the covalent ...
Interplay between dihydrogen and alkali–halogen bonds: Is there some covalency upon complexation of ternary systems?
(Brasil, 2012)
In this study, a theoretical investigation of traditional dihydrogen bonds and novel alkali–halogen bonds was performed in relation to the formation of NaH⋯HCF3 and NaH⋯HCCl3 binary and NaH⋯2(HCF3) and NaH⋯2(HCCl3) ternary ...
A química supramolecular de complexos pirazólicos
(Sociedade Brasileira de Química, 2014)
Improving the properties of chitosan as support for the covalent multipoint immobilization of chymotrypsin
(American Chemical Society, 2008-07)
Changing gel structure and immobilization conditions led to a significant improvement in the covalent multipoint attachment of chymotrypsin on chitosan. The use of sodium alginate, gelatin, or κ-carrageenan, activation ...
Rational design of covalently bridged [FeIII 2M IIO] clusters
(Royal Society of Chemistry, 2010-03)
We are reporting the first supramolecular dimeric units of basic carboxylates. The neutral [FeIII 2MIIO] motif for different 3d M metals is covalently bound through 2,2′-bipyrimidine. We have structurally characterized the ...
Covalent Anchoring and Interfacial Reactions of Adsorbed Porphyrins on Rutile TiO2(110)
(American Chemical Society, 2018-03)
Adsorption of 5-monocarboxyphenyl-10,15,20-triphenylporphyrin (MCTPP) to rutile TiO2(110) at room temperature produces molecules on the surface covalently anchored through the carboxylate group, coadsorbed with hydroxyl ...
Covalent bond orders revisited: The open-shell case
(Royal Society of Chemistry, 2008-06)
This article states the concept of covalent bond order for open-shell systems from the invariance properties of the first- and second-order reduced density matrices for all the components of a multiplet state. A general ...