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The role of the coprecipitation sequence of salt precursors on the genesis of Cu-ZnO-Al2O3 catalysts. synthesis, characterization and activity for low temperature shift reaction
(1998-06)
Cu-ZnO-Al2O3 catalysts for the low-temperature water-gas shift reaction were prepared using methods of direct and reverse coprecipitation. The catalysts obtained were characterized by DRX, TPR, XPS, N2O chemisorption, ...
Productivity and order versus the superficial behavior of the prox reaction on a copper-ceria catalyst Monte Carlo simulations
(Elsevier, 2016)
Monte Carlo simulations for the productivity and order of the PROX/copper-ceria catalyst reaction with different superficial %Cu are made. The results are correlated with the behavior of the different surface species (CO, ...
Copper Nanoparticles Supported on Zinc Oxide as Efficient Catalyst for the N-Arylation of (Hetero)cyclic and Acyclic Amides
(Wiley-VCH, 2021-05-14)
Copper nanoparticles (CuNPs) supported on ZnO are a highly active and selective heterogeneous catalyst for the N-arylation of cyclic and acyclic amides (Golberg coupling). The reaction conditions are mild, featuring K3PO4 ...
Insights into the Preparation of Copper Catalysts Supported on Layered Double Hydroxide Derived Mixed Oxides for Ethanol Dehydrogenation
(2021-06-09)
Acetaldehyde is an important chemical commodity and a building block for producing several other high-value products in the chemical industry. This has motivated the search for suitable, efficient, stable, and selective ...
The importance of copper placement in chiral catalysts supported on heteropolyanions: Lacunary vs external exchanged
(Elsevier, 2020-03-03)
Lacunary [PCuW11O39]5− species modified with chiral bis(oxazoline) leads to very poor results as catalyst in theenantioselective cyclopropanation, in contrast with the Cu-bis(oxazoline) complex exchanged on the Keggin[PW12O40]3− ...
Preparation and characterization of wet-proofed CuO/Al2O 3 catalysts for the oxidation of phenol solutions
(Springer, 2005-06-25)
Two wet-proofed catalysts were prepared by subsequent coating steps with polytetrafluoroethylene fibers over a CuO/γAl2O3 catalyst. They were tested for the oxidation of phenol solutions in a semi-batch reactor. Phenol ...
Conventional and wet proofed CuO/Al2O3 catalysts for phenol oxidation: Deactivation studies in a trickle bed reactor
(John Wiley & Sons Ltd, 2007-05)
A large variety of catalytic systems have been studied for the catalytic wet air oxidation of phenolic solutions. Most of them show good activity, but serious stability problems. In this contribution, stability studies ...
Copper nanoparticles supported on zinc oxide as efficient catalyst for the N-Arylation of (Hetero)cyclic and acyclic amides
(WILEY-V C H VERLAG GMBH, 2021)
Copper nanoparticles (CuNPs) supported on ZnO are highly active and selective heterogeneous catalyst for the N-arylation of cyclic and acyclic amides (Golberg coupling). The reaction conditions are mild, featuring K3PO4 ...
Liquid phase hydrogenation of cinnamaldehyde on Cu-based catalysts
(Elsevier Science, 2003-08)
The liquid phase hydrogenation of cinnamaldehyde was studied at 393 K and 10 bar on Cu-based catalysts containing about 12 wt.% of copper. Cu/SiO 2 was prepared by incipient wetness impregnation while Cu-Al, Cu-Zn-Al, and ...