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Photoinduced organometallic mediating radical polymerization of acrylates mediated by CoII complexes of non-symmetrical tetradentate Schiff-base ligands
(2022-01-15)
Three new cobalt(II) complexes with non-symmetrically-substituted N2O2 tetradentate Schiff-base ligands, prepared from the 1:1:1 condensation of 3-etoxy-salicylaldehyde, salicylaldehyde and ethylenediamine (H2Etsal − 1), ...
Evaluation of the Oxo-bridged Dinuclear Ruthenium Ammine Complex as Redox Mediator in an Electrochemical Biosensor
(2016-03-01)
The mediation of electron-transfer by oxo-bridged dinuclear ruthenium ammine [(bpy)2(NH3)RuIII(μ-O)RuIII(NH3)(bpy)2]4+ for the oxidation of glucose was investigated by cyclic voltammetry. These ruthenium (III) complexes ...
Synthesis of cobalt(II)-α-diimines complexes and their activity as mediators in organometallic mediated radical polymerization of vinyl acetate
(2018-02-24)
This study describes the synthesis and characterization of three α-diimine-cobalt complexes of the type [CoCl2(R-DAB)] (R-DAB = R–N[dbnd]CH–CH[dbnd]N–R; R = Mes, Dipp and Dipp∗) and their application as mediators for the ...
The role of performance measure noise in mediating the relation between task complexity and outsourcing
(American Accounting Association, 2010)
This paper examines the effect of task complexity on a firm’s decision to
outsource and the mediating role of performance measure noise. Using insights from
agency and transaction cost economics theories, we predict that ...
Appropriation of information, knowledge construction and the role of mediator
(2018-09-01)
Knowledge construction is a complex process in which the widespread use of the term information is not, by itself, sufficient to cover its nuances. This leads to a host of discussions of the importance of appropriation of ...
A Downy Mildew Effector Attenuates Salicylic Acid–Triggered Immunity in Arabidopsis by Interacting with the Host Mediator Complex
(Public Library Science, 2013-12-10)
Plants are continually exposed to pathogen attack but usually remain healthy becausethey can activate defences upon perception of microbes. However, pathogens haveevolved to overcome plant immunity by delivering effectors ...
Perceptions on cultural mediation in libraries concerning/Related to national and international literature
(Pontificia Universidade Catolica Campinas, 2017-05-01)
In recent decades the term mediation has been gaining increasing attention in studies and research in Information Science. However, although mediation is a concept studied in Information Science, it is still incipient in ...
Photocontrolled reversible-deactivation radical polymerization of butyl acrylate mediated by Salen-type CoII complexes
(2021-10-05)
In this study, we synthesized the complex [Co(BuSalen)] using the novel tetradentate BuSalen ligand and analyzed its ability as a controlling agent for the photo-induced organometallic-mediated radical polymerization ...
Mediator complex component MED13 regulates zygotic genome activation and is required for postimplantation development in the mouse
(Oxford University Press, 2018-04)
Understanding factors that regulate zygotic genome activation (ZGA) is critical for determining how cells are reprogrammed to become totipotent or pluripotent. There is limited information regarding how this process occurs ...
Cultural mediation and libraries: conceptual perspectives in the Science of Information in Brazil
(Univ Federal Santa Catarina, 2019-01-01)
It presents the conceptual perspectives on cultural mediation in libraries in the scientific production of Information Science in Brazil. It explores the Database of Periodicals in Information Science (BRAPCI), the Brazilian ...