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Structural and spectroscopic evidence of strong electronic delocalization through a cyanido bridge in a mixed-valence Os-Ru complex

Rossi, Melina Brenda; Abboud, Khalil A.; Alborés, Pablo; Baraldo Victorica, Luis Mario (Wiley VCH Verlag, 2010-12)

We report the properties of a trinuclear cyanido-bridged complex, trans-(dmap)4RuII(Âμ-NC)OsIII(CN) 524- [14-; dmap = 4-(dimethylamino)pyridine], whose structure and electronic and vibrational spectra present strong evidence ...

Design of 3d-4f molecular squares through the [Fe{(HB(pz)3)}(CN)3]- metalloligand

Maria-Gabriela Alexandru; Diana Beatrice Visinescu; Sergiu Shova; Willian Xerxes Coelho Oliveira; Francesc Lloret; Miguel Julve (Universidade Federal de Minas GeraisBrasilICX - DEPARTAMENTO DE QUÍMICAUFMG, 2018)