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The aromatic carbon-carbon ipso-substitution reaction
(Wiley VCH Verlag, 2010-12)
The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based ...
Proposal of a simple and effective local reactivity descriptor through a topological analysis of an orbital-weighted fukui function
(John Wiley and Sons Inc., 2017)
Relationship between the electrophilicity of substituting agents and substrate selectivity in Friedel-Crafts reactions
(PERGAMON-ELSEVIER SCIENCE, 2005-01-24)
The global electrophilicity index evaluated at the ground state of benzylating and acylating agents shows a quantitative linear relationship with the experimental substrate selectivity index evaluated for a series of ...
Changes in the SNAr reaction mechanism brought about by preferential solvation
(Royal Soc Chemistry, 2015)
We herein report an experimental and theoretical study on preferential solvation effects for the reactions of 1-fluoro and 1-chloro-2,4-dinitrobenzene towards morpholine in acetonitrile, water and mixtures of them of varying ...