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Specific nucleophile-electrophile interactions in nucleophilic aromatic substitutions
(ROYAL SOC CHEMISTRY, 2013)
Specific nucleophile-electrophile interactions in nucleophilic aromatic substitutions
(ROYAL SOC CHEMISTRY, 2013)
Aromatic nucleophilic substitution in aprotic solvents using hydrogen-bonded biological amines; kinetics studies and quantum chemical calculations
(Wiley, 2015-12)
Intermolecular and intramolecular non-bonding interactions play a crucial role in determining physical and biological properties of relevant amines, and we have recently reported that they are also responsible for changing ...
Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
(Royal Society of Chemistry, 2014)
Solvation effects on the reaction mechanism of the title reactions have been kinetically evaluated in 21 conventional solvents and 17 ionic liquids. Solvent polarity affects the catalyzed and non-catalyzed SNAr pathways ...
Mechanistic pathways of aromatic nucleophilic substitution in conventional solvents and ionic liquids
(Royal Society of Chemistry, 2014)
Solvation effects on the reaction mechanism of the title reactions have been kinetically evaluated in 21 conventional solvents and 17 ionic liquids. Solvent polarity affects the catalyzed and non-catalyzed SNAr pathways ...
Specific nucleophile–electrophile interactions in nucleophilic aromatic substitutions
(Royal Society of Chemistry, 2013)
We herein report results obtained from an integrated experimental and theoretical study on aromatic nucleophilic substitution (S(N)Ar) reactions of a series of amines towards 1-fluoro-2,4-dinitrobenzene in water. Specific ...
Specific nucleophile–electrophile interactions in nucleophilic aromatic substitutions
(Royal Society of Chemistry, 2013)
We herein report results obtained from an integrated experimental and theoretical study on aromatic nucleophilic substitution (S(N)Ar) reactions of a series of amines towards 1-fluoro-2,4-dinitrobenzene in water. Specific ...
REACTIVITY AND STERIC EFFECTS IN SNAR REACTIONS OF PYRIDINE AND METHYLPYRIDINES WITH 4-CHLORO-1-ETHYLPYRIDINIUM TETRAFLUOROBORATE
(Royal Soc ChemistryCambridgeInglaterra, 1992)