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The aromatic carbon-carbon ipso-substitution reaction
(Wiley VCH Verlag, 2010-12)
The aim of this review is to illustrate what we have dubbed an aromatic carbon-carbon ipso-substitution reaction in which a new Ar-C bond is formed at the expense of another Ar-C bond. The potentiality of several C-based ...
Exploring the Potential Energy Surface of Medium-Sized Aromatic Polycyclic Systems with Embedded Planar Tetracoordinate Carbons: A Guided Approach
(Multidisciplinary Digital Publishing Institute (MDPI), 2023-09)
This study scrutinizes the complexities of designing and exploring the potential energy surfaces of systems containing more than twenty atoms with planar tetracoordinate carbons (ptCs). To tackle this issue, we utilized ...
Hierarchy of Carbon Source Utilization in Soil Bacteria: Hegemonic Preference for Benzoate in Complex Aromatic Compound Mixtures Degraded by Cupriavidus pinatubonensis Strain JMP134.
Cupriavidus pinatubonensis JMP134, like many other environmental bacteria, uses a range of aromatic compounds as carbon sources. Previous reports have shown a preference for benzoate when this bacterium grows on binary ...
Induced magnetic field in sp-hybridized carbon rings: Analysis of double aromaticity and antiaromaticity in cyclo[2: N] carbon allotropes
(Royal Society of Chemistry, 2020)
A Reformulated Aromaticity Index Equation Under Consideration For Non-aromatic And Non-condensed Aromatic Cyclic Carbonyl Compounds
(PERGAMON-ELSEVIER SCIENCE LTDOXFORD, 2016)
Aromaticity Survival in Hydrofullerenes: The Case of C66H4 with Its π-Aromatic Circuits
(Wiley-VCH Verlag, 2020-10-22)
The isolated-pentagon rule (IPR) is a determining structural feature that accounts for hollow fullerene stabilization and properties related to Cn (n≥60) cages. The recent characterization of an unprecedented non-IPR ...
Alternation of aromatic-nonaromatic rings in belt-like structures. The behavior of [6.8](3)cyclacene in magnetic fields
(Royal Soc Chemistry, 2015)
[6.8](3)Cyclacene is an interesting belt-like structure displaying aromatic-non-aromatic
alternation, which is useful to gain an understanding of the intramolecular and intermolecular
interactions between the anisotropic ...
Analysis of Local and Global Aromaticity in Si3C5 and Si4C8 Clusters. Aromatic Species Containing Planar Tetracoordinate Carbon
(Multidisciplinary Digital Publishing Institute, 2021-12)
The minimum energy structures of the Si3C5 and Si4C8 clusters are planar and contain planar tetracoordinate carbons (ptCs). These species have been classified, qualitatively, as global (π) and local (σ) aromatics according ...
Biodegradation of aromatic compounds by a halophilic archaeon isolated from the dead sea
(Italian Association of Chemical Engineering, 2014)