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Van der Waals interactions in the self-assembly of 5-amino[6]helicene on Cu(100) and Au(111)
(Royal Society of Chemistry, 2014-09-22)
A combination of Scanning Tunnelling Microscopy and Density Functional
Theory simulations highlights the role of van der Waals interactions in
the self-assembly of an aminohelicene on Cu(100) and Au(111).
Synthesis, properties, and two-dimensional adsorption characteristics of 5-amino[6]hexahelicene
(Willy, 2016)
A convergent synthesis of racemic 5-amino[6]hexahelicene
is described. Cross-coupling reactions are used to
assemble a pentacyclic framework, and a metal-catalyzed
ring-closure comprises the final step. The enantiomers ...