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Quantification of active sites for the determination of methanol oxidation turn-over frequencies using methanol chemisorption and in situ infrared techniques. 1: Supported metal oxide catalysts
(American Chemical Society, 2001-10)
Methanol oxidation over metal oxide catalysts is industrially important for the production of formaldehyde, but knowledge about the intrinsic catalysis taking place is often obscured by a lack of knowledge as to the number ...
Quantitative determination of the number of surface active sites and the turnover frequency for methanol oxidation over bulk metal vanadates
(Elsevier Science, 2003-02)
The present work investigates the number and nature of the surface active sites, selectivity and turnover frequency towards methanol selective oxidation of a series of bulk metal vanadates. The catalysts were synthesized ...