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Palladium-catalyzed arsination reactions and their applications on the synthesis of arsine ligands
(Bentham Science Publishers, 2018-10)
In the synthesis of new ligands for metal-catalyzed reactions, arsines are attracting particular attention, because arsine ligands have been shown to be better ligands than structurally related phosphines in several catalyzed ...
Highly efficient palladium-catalyzed arsination. Synthesis of a biphenyl arsine ligand and its application to obtain perfluoroalkylarsines
(American Chemical Society, 2009-12)
An efficient one-pot, two-step Pd-catalyzed arsination with n-Bu 3SnAsPh2 (1) and sterically hindered aryl iodides (ArI) with different functional groups is reported. The cross-coupling reactions of this stannane with ArI ...
Highly Efficient Palladium-Catalyzed Arsination on the Way to Arsine Ligands
(Teknoscienze Publisher, 2011-06)
Since arsines are drawing particular attention as ligands in metal-catalyzed reactions, the development of new methods to obtain organoarsines is increasingly recognized as central in the synthesis of new ligands. Transition ...
Synthesis of biphenyl-based arsine ligands by Suzuki-Miyaura coupling and their application to Pd-catalyzed arsination
(Royal Society of Chemistry, 2011-09)
A versatile and efficient approach for the synthesis of new biphenyl-based arsine ligands, by a Pd-catalyzed arsination to introduce the -AsPh2 moiety, and then a Suzuki-Miyaura cross-coupling for biaryl construction is ...
A Chiral Bis(arsine) Ligand: synthesis and applications in Palladium catalyzed asymmetric Allylic Alkylations
(American Chemical Society, 2013)
Bulky monodentate biphenylarsine ligands: Synthesis and evaluation of their structure effects in the palladium-catalyzed Heck reaction
(Wiley VCH Verlag, 2015-04)
Biphenyl-based arsine ligands were prepared in two-step fashion by Pd-catalyzed arsination and microwave-assisted Suzuki-Miyaura coupling, providing sterically demanding arsine ligands in overall isolated yields up to 82 ...
Autocatalytic influence of different levels of arsine on the thermal stability and pyrolysis of polypropylene
(ElsevierNetherlands, 2022)
The structure of the nitrosyl [RuCl3(NO)(AsPh3)2] complex
(1995-04-01)
The structure of the title compound, [RuCl3(NO)(AsPh3)2], has been determined by X-ray diffraction. The ruthenium atom is octahedrally coordinated with the arsine ligands in the trans configuration. The ν(NO) was found at ...