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First report on the kinetics of the uncatalyzed esterification of cellulose under homogeneous reaction conditions: a rationale for the effect of carboxylic acid anhydride chain-length on the degree of biopolymer substitution
(SPRINGERDORDRECHT, 2012)
The kinetics of the homogeneous acylation of microcrystalline cellulose, MCC, with carboxylic acid anhydrides with different acyl chain-length (Nc; ethanoic to hexanoic) in LiCl/N,N-dimethylacetamide have been studied by ...
N-acylation of lactams derived from natural 2-benzoxazolinones and 1,4-benzoxazin-3-ones
(Sociedad Chilena de Quimica, 1999)
The N-acylation reaction of a series of lactams of biological interest, derived from 2-benzoxazolinones and 1,4-benzoxazin-3-one, with acetic anhydride has been studied. The reaction yields show the same tendency as that ...
Simple method for high purity acylated steryl glucosides synthesis
(Wiley VCH Verlag, 2016-05)
The present work covers an important gap in the field of analytic standards synthesis of the plants minor component, the acyl steryl glucosides (ASG). A simple and powerful procedure that allows the synthesis of different ...
Gas phase acylation of guaiacol with acetic acid on acid catalysts
(Elsevier Science, 2020-12)
Gas phase acylation of guaiacol on acid solids was studied using catalysts with different acid site density, nature and strength. The main products formed were acetovanillone, 2-acetoxyanisole and catechol using acetic ...
Friedel Crafts Acylation
(Khan Academy, 2016)
Friedel Crafts Acylation
(Khan Academy, 2013)
Gas-phase synthesis of hydroxyacetophenones by acylation of phenol with acetic acid
(Elsevier Science, 2004-09)
The gas-phase synthesis of aromatic ketones via acylation of phenol with acetic acid was studied on SiO2–Al2O3, Al-MCM-41, zeolites HY and ZSM5, and tungstophosphoric acid (HPA) supported on MCM-41 and carbon. At contact ...
Acylation of phenol on solid acids: Study of the deactivation mechanism
(Elsevier Science, 2005-10)
The deactivation mechanism of the gas-phase synthesis of o-hydroxyacetophenone (o-HAP) via acylation of phenol with acetic acid was studied on Al-MCM-41 and zeolites HY, HBeta and HZSM-5. The o-HAP yield remained constant ...
An insight on acyl migration in solvent-free ethanolysis of model triglycerides using Novozym 435
(Elsevier Science, 2016-01-12)
In this work, the ethanolysis of triglycerides catalyzed by immobilized lipase was studied, focusing on the secondary reaction of acyl migration. The catalytic tests were performed in a solvent-free reaction medium using ...