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New insights into the reactivity of 2-halo-glycals: Synthesis of novel iodinated O- and S-glycosides
(Pergamon-Elsevier Science Ltd, 2021-10-09)
We present the selective synthesis of new 2-iodo-2,3-unsaturated O- and S-glycosides. This is the first report on the Ferrier rearrangement of 2-halo-glycals with S-nucleophiles. We obtained α-glycosides in good yields and ...
Synthesis and structure of novel iodinated N-glycosyl-sulfonamides through Aza-Ferrier reaction of 2-substituted glycals
(Elsevier, 2020-09-03)
We obtained a series of novel N-(2-iodo-2,3-dideoxy-2-en-glycopyranosides)-sulfonamides via the Aza-Ferrier rearrangement of protected-2-iodoglycals in good yields and high stereoselectivity. Their structure and conformation ...