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Transposición de Wagner-Meerwein de rasteviol
(Universidad Michoacana de San Nicolás de Hidalgo, 2020-02)
The tricyclic sesquiterpene (1R,3R,4S,5S,7S,8S,9S,10R,11R)-7,8-diangeloyloxylongipinan-1,9-diol, or rasteviol (10), underwent multiple Wagner-Meerwein molecular rearrangements and several hydride shifts when treated with ...