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Biomimetic Growth of Metal–Organic Frameworks for the Stabilization of the Dentin Matrix and Control of Collagenolysis
(2022-02-01)
The dentin matrix is a collagenous scaffold structurally involved in anchoring resin-based materials to the tooth. Time-dependent degradation of this scaffold at the resin–dentin interface remains a core problem in adhesive ...
Construction of a series of rare earth metal-organic frameworks supported by thiophenedicarboxylate linker: Synthesis, characterization, crystal structures and near-infrared/visible luminescence
(2016-01-01)
Six novel rare earth metal organic-frameworks with the general formula {[RE2(2,5-tdc)3(dmso)2]·H2O}n(RE = YIII, PrIII, NdIII, SmIII, ErIIIand TmIII; 2,5-tdc2− = 2,5-thiophenedicarboxylate anion; dmso = dimethylsulfoxide) ...
A novel near monochromatic red emissive europium(III) metal-organic framework based on 1,2,4,5-benzenetetracarboxylate: From synthesis to photoluminescence studies
(2017-09-01)
This work presents the synthesis, solid state characterization (infrared spectroscopy, thermal analysis (TGA/DTA), powder and single crystal X-ray diffraction) and photoluminescence studies of a new europium metal-organic ...
Nanoarchitectonics of metal organic frameworks and PEDOT layer-by-layer electrodes for boosting oxygen reduction reaction
(Royal Society of Chemistry, 2021-09)
We present a strategy for the integration of three building blocks in a functional interfacial nano- architecture in order to fabricate composite films with improved features towards the electrochemical oxygen reduction ...
The chemistry of CO2 capture in an amine-functionalized metal-organic framework under dry and humid conditions
(American Chemical Society, 2017-09-17)
The use of two primary alkylamine functionalities covalently tethered to the linkers of IRMOF-74-III results in a material that can uptake CO2 at low pressures through a chemisorption mechanism. In contrast to other primary ...
Sonocrystallization of zeolitic imidazolate frameworks (ZIF-7, ZIF-8, ZIF-11 and ZIF-20)
(Royal Society of Chemistry, 2012-02)
Zeolitic imidazolate frameworks ZIF-7, ZIF-8, ZIF-11 and ZIF-20 have been synthesized by sonocrystallization. In general, crystals obtained at lower temperatures and shorter times are smaller and have a narrower size ...