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Pairing and unpairing electron densities in organic systems: Two-electron three center through space and through bonds interactions
(American Institute of Physics, 2014-05)
Two-electron three-center bonding interactions in organic ions like methonium (CH
+
5
), ethonium (C2H
+
7
), and protonated alkanes n−C4H
+
11
isomers (butonium cations) are described and characterized within ...
Hydrogenation of Multiple Bonds by Geminal Aminoborane-Based Frustrated Lewis Pairs
(Wiley-VCH, 2018-06-21)
The hydrogenation reaction of multiple bonds that is mediated by geminal aminoborane-based frustrated Lewis pairs (FLPs) has been explored by means of density functional theory calculations. It was found that the release ...
Electronic structure and effectively unpaired electron density topology in closo -Boranes: Nonclassical three-center two-electron bonding
(American Chemical Society, 2011-07)
This article provides a detailed study of the structure and bonding in closo-borane cluster compounds X2B3H3 (X = BH-, P, SiH, CH, N), with particular emphasis on the description of the electron distribution using the ...
Do Organo-Metallic CH4-Me+p Adducts and X4H+ (X=P, As) Clusters Undergo Two-Electron Three-Center Interactions? Some Aspects of Discussion
(American Chemical Society, 2015-06)
Most of the systems possessing true two-electron three-center interactions are electron deficient compounds like boron hydrids, closo-boranes, and some organic ions such as butonium cations. In this work, we perform a ...
A review of history, production and storage of hydrogen
(Corporación Universidad de la Costa, 2022)
Tandem Reactions in Organic Synthesis: The Artistic Approach in Modern Organic Chemistry
(Universidad Militar Nueva Granada, 2016)
Oxidative chemical beneficiation of low-quality coals under low-energy ultrasonic and microwave irradiation: an environmental-friendly approach
(Corporación Universidad de la Costa, 2021)