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A protic ionic liquid, when entrapped in cationic reverse micelles, can be used as a suitable solvent for a bimolecular nucleophilic substitution reaction
(Royal Society of Chemistry, 2016-02)
In this work, we have explored how the confinement of the protic ionic liquid (IL) ethylammonium nitrate (EAN) inside toluene/benzyl-n-hexadecyldimethylammonium chloride (BHDC) reverse micelles (RMs) affects the Cl- ...
Non-aqueous reverse micelles created with a cationic surfactant: Encapsulating ethylene glycol in BHDC/non-polar solvent blends
(Elsevier Science, 2016-11)
We present results on a new system that forms non-aqueous reverse micelles (RMs) created with a cationic surfactant, benzyl-n-hexadecyldimethylammonium chloride (BHDC), encapsulating ethylene glycol (EG), in different ...
Characterization of anionic reverse micelles formulated on biobased solvents as replacing conventional nonpolar organic solvents
(American Chemical Society, 2020-04)
Two reverse micelles (RMs) employing 1,4-bis-2-ethylhexylsulfosuccinate (AOT) and two biobased solvents, p-cymene (p-cym) or limonene (lim), have been formulated with the aim to obtain systems more environmentally friendly. ...
Electron donor ionic liquids entrapped in anionic and cationic reverse micelles. Effects of the interface on the ionic liquid–surfactant interactions
(Royal Society of Chemistry, 2013-08)
The behavior of two ionic liquids (ILs) with high electron donor ability such as 1-butyl-3-methylimidazolium trifluoromethanesulfonate (bmimTfO) and 1-butyl-3-methylimidazolium trifluoroacetate (bmimTfA) entrapped in anionic ...
Subtleties of catanionic surfactant reverse micelle assemblies revealed by a fluorescent molecular probe
(IOP Publishing Ltd, 2017-12)
In this work, the absorption and emission behavior of the cationic hemicyanine trans-4-[4(dimethylamino)styryl]-N-methylpyridinium iodide (HC) in reverse micelles (RMs) formed by the catanionic surfactants benzyl-n-hexad ...
Imim-DEHP reverse micelles investigated with two molecular probes reveals how are the interfacial properties and the coordination behavior of the surfactant
(Elsevier Science, 2020-09)
Aqueous reverse micelles (RMs) generated with the ionic liquid (IL)-surfactant 1-methylimidazolium bis-(2-ethylhexyl)phosphate (imim-DEHP) and the biocompatible solvents methyl laurate (ML) and isopropyl myristate (IPM) ...
Effect of Confinement on the Properties of Sequestered Mixed Polar Solvents: Enzymatic Catalysis in Nonaqueous 1,4-Bis-2-ethylhexylsulfosuccinate Reverse Micelles
(Wiley VCH Verlag, 2016-06)
The influence of different glycerol, N,N-dimethylformamide (DMF) and water mixtures encapsulated in 1,4-bis-2-ethylhexylsulfosuccinate (AOT)/n-heptane reverse micelles (RMs) on the enzymatic hydrolysis of 2-naphthyl acetate ...
Catanionic reverse micelles as an optimal microenvironment to alter the water electron donor capacity in a SN2 reaction
(American Chemical Society, 2019-02)
The effect of interfacial water entrapped in two types of catanionic reverse micelles (RMs) on the kinetic parameters of the SN2 reaction between dimethyl-4-nitrophenylsulfonium trifluoromethanesulfonate (S+) and n-butylamine ...
The Use of AOBH-DEHP Molecular Probe to Characterize BHDC Reverse Micelles Interfaces. Insights on the Interfacial Water Structure
(Wiley, 2017-03)
This work presents the use of the molecular probe: 3,6-bis(dimethylamino) acridinium bis-(2-ethylhexyl) phosphate salt, AOBH-DEHP. This probe is used to gain insights into the properties of the benzene/benzyl-n-hexadecyl ...
Photophysics of thionine in AOT and BHDC reverse micelles. Quenching of the triplet state by aliphatic amines studied by transient absorption spectroscopy
(Elsevier Science Sa, 2017-09)
The photophysics of thionine (3,7-diamino-5-phenothiazinium) (Th+) was investigated in reverse micelles (RMs) of sodium bis(2-ethylhexyl)sulfosuccinate (AOT) and benzyldimethylhexadecylammonium chloride (BHDC) with special ...