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Síntese e caracterização fotofísica de complexos polipiridínicos de Re(I) baseados no ligante 1,2-bis(4-piridil)etanoSíntese e caracterização fotofísica de complexos polipiridínicos de Re(I) baseados no ligante 1,2-bis(4-piridil)etano
(Universidade Federal de UberlândiaBRPrograma de Pós-graduação em QuímicaCiências Exatas e da TerraUFU, 2016)
Solvent effects on the photophysical properties of Bu4N[(4,4′-bpy)Re(CO)3(bpy-5,5′-diCOO)] complex. A combined experimental and computational study
(Elsevier Science Sa, 2016-08)
The photophysical properties of the complex Bu4N[(4,4′-bpy)Re(CO)3(bpy-5,5′-diCOO)] were studied in protic and aprotic media with the aid of steady-state and time-resolved techniques and TD-DFT calculations. The absorption ...
Synthesis and characterization of monometallic and bimetallic complexes of rhenium(I) and ruthenium(II) with 4,4 '-bipyridine as ligand-bridge.
(SOCIEDAD CHILENA DE QUIMICA, 2002-12)
A new Rhenium (I) and Ruthenium(II) bimetallic polipyridilcarbonil complex and the corresponding monometallic precursor complexes were prepared. The compounds were characterized physically and spectroscopically (Elemental ...
Tuning the photophysical properties of a (P,N)Re-I complex by adding a -NH- fragment into a P,N-bidentate ligand: The case of [P,N{(C6H5)(2)(C5H4N)NHPRe(CO)(3)Br]
(Elsevier, 2016)
The spectroscopic, electrochemical and photophysical properties of the new complex [P,N-{(C6H5)(2)(C5H4N)NHP)Re(CO)(3)Br] (RePNN) are reported. The UV-Vis spectrum in dichloromethane (DCM)' shows an absorption maximum ...
Norharmane ReI(CO)3(L)+ complexes, L=2,2-bipyridine or 1,10-phenanthroline: Synthesis, structural and spectroscopic characterization
(Royal Society of Chemistry, 2015-08)
Two novel Re(I) complexes with the general formula fac-[Re(CO)3(L)(nHo)]CF3SO3, where L = 2,2′-bipyridine (bpy) or 1,10 phenanthroline (phen) and nHo (9H-pyrido[3,4-b]indole; norharmane) have been synthesized. The Re(I)–nHo ...
Photochemical C-C1 bond activation of trichloroarenes by the rhenium complex (n5-C5ME5)Re(CO)3. X-ray structure of trans-(n5-C5Me5)Re(CO)2(2-methoxy-4,5-dichlorophenyl)cloride.
(2003)
Photochemical reaction of (eta(5)-C5Me5)Re(CO)(3), with 2,4,5-trichloroanisole and 3,4,5-trichlorotrifluoromethylbenzene yields (eta(5)- C5Me5)Re(CO)(2)(C6H2Cl2(MeO))Cl (1) and (eta(5)-C5Me5)Re(CO)(2)(C6H2Cl2(CF3))Cl, (2) ...
An amine linker group modulates luminescent properties in a Rhenium(I) tricarbonyl complex. How can it be applied for ratiometric oxygen sensing?
(Elsevier, 2020-01)
The UV–Vis absorption spectrum of the rhenium(I) tricarbonyl complex [(NH2-phen)Re(CO)3Br] (ReNN-NH2Br, a deep-orange solid) in solution shows three bands located at 300, 370 and 445 nm. TD-DFT calculations and spectroscopic ...
Nitrile hydrolysis in a rhenium(I)-ruthenium(III) dinuclear complex
(Taylor & Francis Ltd, 2004-05)
Kinetic data for the hydrolysis reaction: [(CO)3(bpy)Re I(4-CNpy)RuIII(NH3)5]4+ + H2O → [(CO)3(bpy)ReI(4-C(O)NHpy)Ru III(NH3)5]3+ + H+ (bpy = 2,2′-bipyridine, 4-CNpy = 4-cyanopyridine and 4-C(O)NHpy = isonicotinamido), ...