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New palladium(II) complexes with pyrazole ligands Part I. Synthesis, spectral and thermal studies, and antitumor evaluation
(Springer, 2011-11-01)
The pyrazole ligand 3,5-dimethyl-4-iodopyrazole (HdmIPz) has been used to obtain a series of palladium(II) complexes (1-4) of the type [PdX(2)(HdmIPz)(2)] {X = Cl(-) (1); Br(-) (2); I(-) (3); SCN(-) (4)}. All compounds ...
Cycloaddition reaction of the azido-bridged cyclometallated complex [Pd(dmba)N-3](2) with CS2. Crystal and molecular structure of DI(mu, N,S-1,2,3,4-thiatriazole-5-thiolate) bis[(N,N-dimethylbenzyl-amine-C-2,N)palladium(II)]
(Gordon Breach Sci Publ Ltd, 1999-01-01)
The 1,3-dipolar cycloaddition of carbon disulfide to the coordinated azide in the cyclometallated compound [Pd(dmba)(N-3)](2) (1), dmba = N,N-dimethylbenzylamine, was investigated. The compound obtained di(mu, N,S-1,2,3, ...
Synthesis, characterization, and thermal behavior of palladium(II) complexes containing 4-iodopyrazole
(Springer, 2014-09-01)
The mononuclear pyrazolyl complexes [PdCl2(HIPz)(2)] (1), [PdBr2(HIPz)(2)] (2), [PdI2(HIPz)(2)] (3), [Pd(SCN)(2)(HIPz)(2)] (4), and [Pd(NHCOIPz)(2)] (5) have been prepared. Compound 1 was obtained from the displacement of ...
Experimental and DFT Study on the Compounds [PdCl2L2] (L=4-methylpyrazole, 4-iodopyrazole)
(Slovensko Kemijsko Drustvo, 2015-01-01)
Theoretical molecular structures of the complexes [PdCl2(HmPz)(2)] (1) and [PdCl2(HIPz)(2)] (2) (HmPz = 4-methylpyrazole; HIPz = 4-iodopyrazole) were studied using B3LYP/DFT method. The new complex 2 and the complex 1 were ...
Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)
(Springer, 2011-11-01)
The synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)(2)(mtu)(PPh3)] (X = Cl- (1), SCN- (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)(2)(phtu)(PPh3)] (X = Cl- (3), ...
Thermal study of mononuclear Pd(II) complexes of the type [Pd(X)(2)(Rtu)(PPh3)] (X = Cl, SCN; Rtu = N-methylthiourea, N-phenylthiourea)
(Springer, 2011-11-01)
The synthesis, spectroscopic characterization, and thermal analysis of the compounds [Pd(X)(2)(mtu)(PPh3)] (X = Cl- (1), SCN- (2); mtu = N-methylthiourea; PPh3 = triphenylphosphine) and [Pd(X)(2)(phtu)(PPh3)] (X = Cl- (3), ...
Cytotoxic study of organometallic compounds of palladium (II) in mice peritoneal macrophages
(Universidade Estadual Paulista (Unesp), 2005)
Síntese e atividade citotóxica de alguns azido-ciclopaladados estabilizados com ligantes bifosfínicos
(Sociedade Brasileira de Química, 1999-06-01)
Some cyclopalladated compounds containing the azido group ligand and the (C-N) ring of N,N-dimethylbenzylamine have been prepared by bridge opening reactions of dimmer azide complex precursor with some diphosphines in ...
Hydrogenation of N-benzylideneaniline by palladium (II) catalysts with phosphorus-nitrogen ligands using formic acid as a renewable hydrogen source
(Elsevier B.V., 2019)
This paper reports the hydrogenation of N-benzylideneaniline catalysed by Pd(II) compounds containing heterobidentated phosphorus-nitrogen (PN) ligands. The general formulas of the catalysts are cis-[PdCl2(L1)] and ...