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Produtos da química fina através da metátese de propenilbenzenos de origem vegetal empregando catalisadores rutênio-alquilideno
(Universidade Federal de Minas GeraisUFMG, 2017-06-30)
In this work new methodologies with technological potential for high value-added products were developed from biorenewable 1-propenylbenzenes, anethole, isoeugenol and isosafrol, available in abundance in Brazil. This ...
Influence Diagnostics For Grubbs's Model With Asymmetric Heavy-tailed Distributions
(Springer New York LLC, 2014)
Plant Oil Valorization by Cross-Metathesis Reactions: Synthesis of Fine Chemicals From Methyl Oleate
(Planta Piloto de Ingeniería Química, 2020-02)
This work studies the production of high-value compounds by the cross-metathesis of methyl oleate (MO) with ethylene, cinnamonitrile and cinnamaldehyde using the 2nd generation Hoveyda-Grubbs complex (HG) as catalyst, ...
Catalytic valorization of oil-derived fatty esters via cross-metathesis with nitriles
(Wiley VCH Verlag, 2016-11)
The cross-metathesis of methyl oleate with 3-pentenenitrile to obtain 2-undecene, methyl 9-undecenoate, methyl 11-cyano-9-undecenoate and 3-dodecenenitrile was studied at 323 K in a batch reactor using second-generation ...
Alil-aromáticos como matéria prima renovável para produção de arilbutenoatos via metátese cruzada de olefinas
(Universidade Federal de Minas GeraisUFMG, 2014-08-22)
In this work the cross-metathesis reactions of substrates of natural sources (estragole, methyl eugenol, safrole and eugenol) with methyl acrylate using dichloroethane and dimethyl carbonate as solvent were studied employing ...