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Monomer reactivity in functionalized vinyl copolymers: A theoretical approach
(MARCEL DEKKER INC, 2004)
This work studies how the variation of the inter-atomic distance affects the total energy in addition reactions of several vinyl radicals on vinyl monomers. Based on the energetic profiles obtained, the corresponding ...
Copolymers of phenoxyethyl methacrylate with glycidyl methacrylate: Synthesis, characterization and reactivity ratios
(2008)
The free radical copolymerization of phenoxyethyl methacrylate (POEMA) and glycidyl methacrylate (GMA) was carried out using ,'-azobisisobutyronitrile (AIBN) in 2-butanone solution at 3331K. The copolymers were characterized ...
Vapor–liquid equilibrium of copolymer + solvent mixtures: Thermodynamic modeling by two theoretical equations of state
(2006)
Copolymers are increasing their importance from the commercial point of view, mainly due to their tuned physical properties for specific applications in the polymer manufacturing. Copolymers allow tailoring new materials ...
Copolymers of phenoxyethyl methacrylate with butyl methacrylate: Synthesis, characterization and reactivity ratios
(2009)
Phenoxyethyl methacrylate (POEMA) and butyl methacrylate (BMA) were copolymerized by free-radical copolymerization using ,'-azobisisobutyronitrile (AIBN) in 2-butanone solution at 3331K. Copolymers were characterized by ...
Block copolymer concentration gradient and solvent effects on nanostructuring of thin epoxy coatings modified with epoxidized styrene-butadiene-styrene block copolymers
(American Chemical Society, 2012-02)
The gradient on block copolymer concentration through film thickness as well as the effects of casting solvents used on the nanostructuring of a thermosetting epoxy coating modified with an epoxidized poly(styrene-b- ...
Modification of model ethylene-butene copolymers using an organic peroxide
(Elsevier, 2005-01-26)
Well-characterized linear ethylene-butene-1 copolymers with polydispersities lower than 1.1 were modified using an organic peroxide with the purpose of assessing the relative importance of chain-linking processes. The ...
Graft Copolymers for Blend Compatibilization: Mathematical Modeling of the Grafting Process
(Wiley VCH Verlag, 2012-10)
The grafting of PE onto PS through a Friedel-Crafts reaction, which results in a mixture of PE-g-PS copolymer, unmodified PE, and modified PS, is investigated. The copolymer may be suitable for compatibilization of immiscible ...
Thermal characterisation of Boc-aminostyrene/styrene copolymers latexes
(Elsevier Science BvAmsterdamHolanda, 1999)
Cure kinetics of epoxy systems modified with block copolymers
(John Wiley & Sons Ltd, 2004-10)
The kinetics pathway of a 4,4′‐diaminodiphenylmethane‐cured diglycidyl ether of bisphenol‐A (DGEBA) epoxy system modified with a PEO–PPO–PEO block copolymer has been investigated by differential scanning calorimetry. The ...