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Kinetic control of aqueous polymerization using radicals generated in different spin states
(MDPI, 2017-03)
1) Background: Magnetic fields can interact with liquid matter in a homogeneous and instantaneous way, without physical contact, independently of its temperature, pressure and agitation degree and without modifying recipes ...
Theoretical Study about the Effect of Halogen Substitution on the Reactivity of Antitumor 3-Formylchromones and Their Free Radicals
(Hindawi Limited, 2017)
© 2017 Maximiliano Martínez-Cifuentes et al. The mandatory presence of a chlorine atom on the aromatic ring of 6-hydroxy-3-formyl angular chromones, on the respiration inhibition of mammary carcinoma mouse, is explained ...
Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: thermal and photochemical initiation
(Wiley, 2010-10)
The classical radical-based hydrosilylation reaction of organic compounds bearing C[BOND]C multiple bonds is usually carried out in organic solvents and is herein presented in water with both hydrophobic and hydrophilic ...
Biomimetic ketone reduction by disulfide radical anion
(Molecular Diversity Preservation International, 2021-09)
The conversion of ribonucleosides to 2′-deoxyribonucleosides is catalyzed by ribonucleoside reductase enzymes in nature. One of the key steps in this complex radical mechanism is the reduction of the 3′-ketodeoxynucleotide ...
FULLERENE-60 AND PLATINAFULLERENE-60 DERIVATIVES
(Soc Brasileira QuimicaSao PauloBrasil, 1995)
Application of the electron localization function of radical systems
(2003)
An application of the topological electron localization function (ELF) analysis of free radical systems is presented. A separation of the ELF function into its α-spin and β-spin contributions has been performed. Methyl and ...