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Molecular basis of intramolecular electron transfer in proteins during radical-mediated oxidations: Computer simulation studies in model tyrosine-cysteine peptides in solution
(Elsevier Science Inc, 2012-09)
Experimental studies in hemeproteins and model Tyr/Cys-containing peptides exposed to oxidizing and nitrating species suggest that intramolecular electron transfer (IET) between tyrosyl radicals (Tyr-O) and Cys residues ...
Kinetic aspects of ion exchange in KhFek[Fe(CN)(6)](l)center dot mH(2)O compounds: A combined electrical and mass transfer functions approach
(Amer Chemical Soc, 2006-10-05)
The present paper quantifies and develops the kinetic aspects involved in the mechanism of interplay between electron and ions presented elsewhere(1) for KhFek[Fe(CN)(6)](l)center dot mH(2)O (Prussian Blue) host materials. ...
Kinetic aspects of ion exchange in KhFek[Fe(CN)(6)](l)center dot mH(2)O compounds: A combined electrical and mass transfer functions approach
(Amer Chemical Soc, 2006-10-05)
The present paper quantifies and develops the kinetic aspects involved in the mechanism of interplay between electron and ions presented elsewhere(1) for KhFek[Fe(CN)(6)](l)center dot mH(2)O (Prussian Blue) host materials. ...
Cyclic voltammetry and digital simulation of the electroreducction of ortho-and meta-nitro aryl 1,4-dihydropyridines
(Sociedad Chilena de Química, 1999)
Cyclic voltammetry (CV) and digital simulation methods are utilezed to elucidate the mechanism of electrochemical reduction of a series of nitro aryl 1,4-dihydropyridines im protic (aqueous) and mixed media. The experimental ...
Reversible electron pumping and negative differential resistance in two-step barrier diode under strong terahertz ac field
(Amer Inst PhysicsMelvilleEUA, 2011)
Visible light photopolymerization in BHDC reverse micelles: laser flash photolysis study of the photoinitiating mechanism
(Elsevier Science, 2013-02)
The photopolymerization of acrylamide (AA) in reverse micelles (RMs) of benzyl hexadecyl dimethylammonium chloride (BHDC) was investigated. The polymerization was performed by irradiation in the 500 nm region of the spectrum, ...
The Use of AOBH-DEHP Molecular Probe to Characterize BHDC Reverse Micelles Interfaces. Insights on the Interfacial Water Structure
(Wiley, 2017-03)
This work presents the use of the molecular probe: 3,6-bis(dimethylamino) acridinium bis-(2-ethylhexyl) phosphate salt, AOBH-DEHP. This probe is used to gain insights into the properties of the benzene/benzyl-n-hexadecyl ...
Structural, electronic, and thermochemical preference for multi-PCET reactivity of ruthenium(II)-amine and ruthenium(IV)-amido complexes
(Wiley VCH Verlag, 2021-10-21)
The multiredox reactivity of bioinorganic cofactors is often coupled to proton transfers. Here we investigate the structural, thermochemical, and electronic structure of ruthenium-amino/amido complexes with multi- ...
Role of Ruthenium Oxidation States in Ligand-to-Ligand Charge Transfer Processes
(American Chemical Society, 2012-01)
We describe in this paper the properties of [RuII/III(bpy)2ClL]+1/+2 and [RuII/III(bpy)2L2]+2/+3. L = ditolyl-3-pyridylamine (dt3pya) is a redox active ligand related to triarylamines, which is very similar to 3-aminopyridine ...