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Electron delocalization and charge mobility as a function of reduction in a metal-organic framework
(Nature Publishing Group, 2018-07)
Conductive metal-organic frameworks are an emerging class of three-dimensional architectures with degrees of modularity, synthetic flexibility and structural predictability that are unprecedented in other porous materials. ...
Reversible breaking and forming of Metal-Ligand coordination bonds: Temperature-Triggered Single-Crystal to Single-Crystal transformation in a Metal-Organic framework
(Wiley VCH Verlag, 2009-05)
[Yb(C4H4O4)15] undergoes a temperature-triggered single-crystal to single-crystal transformation. Thermal X-ray single-crystal studies showed a reversibly orchestrated rearrangement of the atoms generated by the ...
Supramolecular chemistry in solid state materials such as metal-organic frameworks
(Science From Israel-division Of Laser Pages Publ Ltd, 2018-10)
Supramolecular chemistry has enriched the scientific research for more than fifty years reaching one of its summits in 2016, when the Chemistry Nobel Prize was awarded for the design and synthesis of molecular machines, ...
Carbon quantum dot surface-chemistry-dependent ag release governs the high antibacterial activity of Ag-metal-organic framework composites
(American Chemical Society, 2018-08)
Nanocomposites and hybrid materials of Ag-1,3,5- benzenetricarboxylic acid metal-organic frameworks (MOFs) with Sand N-carbon quantum dots (CQDs) were synthesized and evaluated for their antibacterial activity against ...
A Gadolinium Metal-Organic Framework Film as a Converter Layer for Neutron Detection
(Wiley VCH Verlag, 2020-10)
Metal-organic frameworks (MOFs) are known for their versatility in terms of their crystalline structure, porosity, resistance to temperature, radiation damage, and luminescence among others. Gadolinium (Gd) is one of the ...
Powering Up the Oxygen Reduction Reaction through the Integration of O 2 -Adsorbing Metal–Organic Frameworks on Nanocomposite Electrodes
(American Chemical Society, 2018-10)
Oxygen reduction reaction (ORR), essential in many energy conversion devices, takes particular relevance in facing the increasing global demand for clean energy sources and vectors. In this context, desirable features for ...
Síntesis y modificación de nanocristales de Redes Metal-Orgánicas (MOFs) para su utilización en procesos de catálisis heterogénea
(2020-03-20)
En los últimos años se ha incrementado el interés en utilizar Redes Metal-Orgánicas (MOFs: “Metal-Organic Frameworks”) para aplicaciones en catálisis, siendo actualmente un tópico de intensa investigación dado que estos ...
A elaboração de um texto de divulgação científica sobre Metal Organic Frameworks para o ensino de química
(Universidade Estadual Paulista (Unesp), 2022-01-21)
The production of scientific knowledge developed in Brazilian universities hardly reaches the society, which causes a distance and devaluation of science by the general public. Science communication practices stand out as ...
Room-Temperature Negative Differential Resistance in Surface-Supported Metal-Organic Framework Vertical Heterojunctions
(2021-09-01)
The advances of surface-supported metal-organic framework (SURMOF) thin-film synthesis have provided a novel strategy for effectively integrating metal-organic framework (MOF) structures into electronic devices. The ...
Effect of Keggin polyoxometalate on Cu(ii) speciation and its role in the assembly of Cu3(BTC)2 metal-organic framework
(Royal Society of Chemistry, 2011-07)
HKUST-1 is one of the popular metal-organic frameworks (MOFs). The formation of this MOF is significantly accelerated by adding Keggin polyoxometalate anions to the synthesis solution. In this paper the chemistry behind ...