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Synthetic organometallic radical chemistry in water
(Bentham Science Publishers, 2009-04)
Several organic radical transformations in aqueous media using organometallic chemistry are presented. Group XIV-elements, such as Si and Ge, and Sn-centered radicals make use of novel methodologies in water which employ ...
KINETICS PROFILES IN THE REACTION OF ABTS DERIVED RADICALS WITH SIMPLE PHENOLS AND POLYPHENOLS
(Sociedad Chilena de Química, 2004)
Mechanistic study of the addition reaction of TeCl(4) to alkynes: Participation of TeCl(3) centered-radical
(ELSEVIER SCIENCE SA, 2008)
The mechanism of the addition reaction of TeCl(4) to alkynes was indirectly established by the detection of TeCl(3) centered radicals using EPR spin trapping, ESI-MS and ESI-MS/MS characterization. Crown Copyright (C) 2008 ...
Radical Arylations
(John Wiley & Sons Ltd, 2012)
This chapter reports on radical arylations also highlighting the very important early achievements on this chemistry. To be named at this place are the Meerwein arylation and the Pschorr reaction. Intramolecular homolytic ...
Competitive reaction pathways for o-Anilide aryl radicals: 1,5-Or 1,6-hydrogen transfer versus nucleophilic coupling reactions. A novel rearrangement to afford an amidyl Radical
(American Chemical Society, 2009-02)
The photoinduced reactions of o-iodoanilides (o-IC6H 4N(Me)COR, 4a-d) with sulfur nucleophiles such as thiourea anion (1, -SCNH(NH2)), thioacetate anion (2, MeCOS-), and sulfide anion (3,S2-) follow different reaction ...
Lysozyme modification by the Fenton reaction and gamma radiation
(TAYLOR & FRANCIS LTD, 2002)
A comparative study was performed on lysozyme modification after exposure to Fenton reagent (Fe(E)/H2O2) or hydroxyl radicals produced by gamma radiation. The conditions were adjusted to obtain, with both systems, a 50% ...
Radical fluorination reactions by thermal and photoinduced methods
(Royal Society of Chemistry, 2017-11)
The radical or radical ion-based fluorination reactions of organic compounds will be presented. These methodologies include fluorination processes accomplished through thermal or photoinduced radical/electron transfer ...
Spectral and kinetic properties of radicals derived from oxidation of quinoxalin-2-one and its methyl derivative
(MDPI AG, 2014)
© 2014 by the authors licensee MDPI Basel Switzerland.The kinetics and spectral characteristics of the transients formed in the reactions of • OH and •N3 with quinoxalin-2(1H)-one (Q), its methyl derivative, 3-methylquinoxalin- ...