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Specific nucleophile-electrophile interactions in nucleophilic aromatic substitutions
(2013)
We herein report results obtained from an integrated experimental and theoretical study on aromatic nucleophilic substitution (SNAr) reactions of a series of amines towards 1-fluoro-2,4-dinitrobenzene in water. Specific ...
ELECTROPHILIC AROMATIC CL+ ADDITION AND CO.+ SUBSTITUTION IN THE GAS-PHASE
(Amer Chemical SocWashington, 1993)
Activation of Electrophile/Nucleophile Pair by a Nucleophilic and Electrophilic Solvation in a SNAr Reaction
(2018)
Nucleophilic aromatic substitution reactions of 4-chloroquinazoline toward aniline and hydrazine were used as a model system to experimentally show that a substrate bearing heteroatoms on the aromatic ring as substituent ...
Advances in metal-assisted non-electrophilic fluoroalkylation reactions of organic compounds
(Elsevier, 2015-02)
Metal-assisted trifluoromethylation and perfluoroalkylation reactions are probably one of the first approaches employed to achieve fluoroalkyl-group substitutions of organic substrates through the use of metals such as ...
Pseudo-Pericyclic Reactions: Aromatic Compound Derivatives as Electrophiles in Polar Diels-Alder Reactions. An Experimental and Theoretical Study
(The Research Trends Editorial, 2014-11)
The Diels-Alder reaction is considered a pericyclic procces. However, depending of the structure of the diene and the dienophile the nature of this reaction can change. In the last years we have worked with aromatic nitro ...