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Studies on homo and copolymerizations of long-chained α-olefins over metallocene catalysts
(2000)
Metallocene catalysts, viz., rac-Et(Ind)2ZrCl2, rac-Me2-Si(Ind)2ZrCl2 and Ph2C(Flu)(Cp)ZrCl2, were studied in homopolymerization of 1-octadecene and the first two were used in copolymerization of ethylene with 1-octadecene. ...
Copolymerization of polypropylene and functionalized linear α-olefin onto glass fibers
(John Wiley & Sons Inc, 2001-08)
This work deals with a novel glass fiber surface modification and subsequent metallocenic propylene polymerization onto it. Experimental results are presented on methylaluminoxane (MAO) fixation at the fiber surface, ...
Preparation of nanocomposites based on styrene/(p-methylstyrene) and SiO2 nanoparticles, through a metallocene–MAO initiating system
(Springer Verlag, 2019)
© 2018, Springer-Verlag GmbH Germany, part of Springer Nature. The preparation of nanocomposites, including styrene, tertbutylstyrene, and SiO2 nanoparticles, in toluene solution was attempted by in situ polymerization ...
Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
(Wiley VCH Verlag, 2013-05-27)
The polymerization that IUPAC terms reversible-deactivation radical polymerization is a controlled radical polymerization technique (CRP) that allows producing polymers with tailored properties without the stringent ...
Magnetic field effects on the copolymerization of water-soluble and ionic monomers
(John Wiley & Sons Inc, 2009-01)
The effect of magnetic field (MF) on the radical copolymerization of a series of water-soluble and ionic monomers is presented including acrylamide (AM), acrylic acid (AA), its ionized form acrylate (A-), and diallyldime ...
Copolymerization between A3 and B2 with ring formation and different intrinsic reactivity in one of the monomers
(American Chemical Society, 2001-06)
We present two models for the stepwise copolymerization between a three-functional monomer As and a bifunctional monomer B2 where both intramolecular reaction and different intrinsic reactivities of reactive sites are ...
Modeling and Simulation of Ethylene and 1-Butene Copolymerization in Solution with a Ziegler-Natta Catalyst
(Berkeley Electronic PressBerkeleyEUA, 2010)