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Rhodium(III) and ruthenium(II) complexes with the chiral phosphine-alcohol PH2PCH2CHMeCH2OH. Synthesis and characterisation
(SOC CHILENA QUIMICA, 2002)
Reaction of the dinuclear complex [{(eta(5)-C5Me5)RhCl}(2)(mu-Cl)(2)] with the chiral phosphine (R)-Ph2PCH2CHMeCH2OH leads to the complex [{(eta(5)-C5Me5)RhCl2(eta(1)-Ph2PCH2CHMeCH2OH-P)}](1). This reaction, in the presence ...
Influence of the bite natural angle of bidentate diphosphine ligands in the syngas-free branched hydroformylation of Β-functionalized olefins
(Elsevier B.V., 2018)
© 2018 Elsevier B.V. The correlation between the activity, regio- and chemoselectivity of Rh-diphosphine catalyst and the ligand bite natural angle (βn) in the syngas-free hydroformylation of allyl cyanide was investigated. ...
Preparation, characterization and electrochemical studies of dinuclear copper(II) complexes with pseudohalides and bidentate amines on platinum electrode in acetonitrile
(1997-12-01)
The complexes: [Cu(N 3) 2(N,N-diEten)] 2, [Cu(N 3) 2(tmeen)] 2, [Cu(N 3)(NCO)(N,N-diEten)] 2, [Cu(N 3) 2(N,N′-diMeen)] 2 and [Cu(N 3)(NCO)(tmeen)] 2 were prepared, characterized and their electrochemical behavior was ...
Preparation, characterization and electrochemical studies of dinuclear copper(II) complexes with pseudohalides and bidentate amines on platinum electrode in acetonitrile
(1997-12-01)
The complexes: [Cu(N 3) 2(N,N-diEten)] 2, [Cu(N 3) 2(tmeen)] 2, [Cu(N 3)(NCO)(N,N-diEten)] 2, [Cu(N 3) 2(N,N′-diMeen)] 2 and [Cu(N 3)(NCO)(tmeen)] 2 were prepared, characterized and their electrochemical behavior was ...
Platinum(II) complexes with dithiolates and phosphinites as ligands: Crystal structure of [Pt{S2CO}{P(OMe)Ph(2)}(2)]
(PERGAMON-ELSEVIER SCIENCE LTD, 1996)
Reaction of the complex [PtCl{P(O)Ph(2)} {P(OH)Ph(2)}(2)] with silver or thallium derivatives of dithiolate ligands led to neutral complexes of general formula [Pt{S-S} {P(O)Ph(2)} {P(OH)Ph(2)}], where {S-S}(-) ={S(2)CNEt(2)}(-) ...
ADDUCTS OF CADMIUM DIETHYLDITHIOCARBAMATE WITH BIDENTATE NITROGEN LIGANDS
(Elsevier Science Sa LausanneLausanne 1Suíça, 1990)
Reaction of [Fe-3(CO)(12)] with bidentate phosphines: Redox behavior of products
(Elsevier Science Sa LausanneLausanneSuíça, 1996)