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Mono, Di and Trifunctional Cyclic Organic Peroxides: The Effect of Substituents and Ring Size on their Thermolysis in 1,4-dioxan
(Csiro Publishing, 2013-07-15)
The thermal decomposition reaction of cyclic organic peroxides was studied in 1,4-dioxan at initial concentrations between ~10–4 and 10–2 mol L–1 and at a temperature interval between 100 and 170°C, according to the thermal ...
Synthesis of Unstable Cyclic Peroxides for Chemiluminescence Studies
(SOC BRASILEIRA QUIMICASAO PAULO, 2012)
Cyclic four-membered ring peroxides are important high-energy intermediates in a variety of chemi and bioluminescence transformations. Specifically, alpha-peroxylactones (1,2-dioxetanones) have been considered as model ...
Synthesis of unstable cyclic peroxides for chemiluminescence studies
(Sociedade Brasileira de Química, 2012)
Cyclic four-membered ring peroxides are important high-energy intermediates in a variety of chemi and bioluminescence transformations. Specifically, α-peroxylactones (1,2-dioxetanones) have been considered as model ...
Effect of ionic liquid on the thermal decomposition of cyclic organic peroxides
(Elsevier Science, 2016-06)
The thermolysis of cyclic diethylketone triperoxide (3,3,6,6,9,9-hexaethyl-1,2,4,5,7,8-hexaoxacyclononane, DEKTP) and cyclic pinacolone diperoxide (3,6-diterbutyl-3,6-dimethyl-1,2,4,5-tetraoxacyclohexane, PDP) was studied ...
Revision of Singlet Quantum Yields in the Catalyzed Decomposition of Cyclic Peroxides
(AMER CHEMICAL SOCWASHINGTON, 2012)
The chemiluminescence of cyclic peroxides activated by oxidizable fluorescent dyes is an example of chemically initiated electron exchange luminescence (CIEEL), which has been used also to explain the efficient bioluminescence ...
Continuous Flow-Processing of Organometallic Reagents Using an Advanced Peristaltic Pumping System and the Telescoped Flow Synthesis of (E/Z)-Tamoxifen
(Amer Chemical SocWashingtonEUA, 2013)