Artículos de revistas
Adsorption Of Lead And Copper Ions From Aqueous Effluents On Rice Husk Ash In A Dynamic System
Registro en:
Brazilian Journal Of Chemical Engineering. Assoc. Brasiliera De Eng. Quimica / Braz. Soc. Chem. Eng., v. 31, n. 2, p. 519 - 529, 2014.
1046632
10.1590/0104-6632.20140312s00002103
2-s2.0-84904859654
Autor
Vieira M.G.A.
De Almeida Neto A.F.
Da Silva M.G.C.
Carneiro C.N.
Filho A.A.M.
Institución
Resumen
This study evaluated the kinetic adsorption of Pb and Cu ions using rice husk ash as adsorbent in a fixed bed. The maximum adsorption capacities obtained for lead and copper ions in the fixed bed were 0.0561 and 0.0682 mmol/g (at 20 °C), respectively. The thermodynamic studies indicated that the lead adsorption process was exothermic and spontaneous, while the copper adsorption process was endothermic and spontaneous. Characterization results indicated the presence of several functional groups, amorphous silica and a fibrous and longitudinal structure of rice husks. Rice husk ash (RHA) from northern Brazil can be used as a bioadsorbent for the individual removal of Pb(II) and Cu(II) ions from metal-containing effluents. 31 2 519 529 Ahmaruzzaman, M., A review on the utilization of fly ash (2010) Prog. Energy Combust. Sci., 36, pp. 327-363 De Almeida Neto, A.F., Vieira, M.G.A., Da Silva, M.G.C., Cu(ii) adsorption on modified bentonitic clays: Different isotherm behaviors in static and dynamic systems (2012) Mater. Res., 15, pp. 114-124 Attia, A.A., Khedr, S.A., Elkholy, S.A., Adsorption of chromium ion (vi) by acid activated carbon (2010) Braz. J. Chem. Eng., 27 (1), pp. 183-193 Bhattacharyya, K.G., Gupta, S.S., Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review (2008) Adv. Colloid Interface Sci., 140, pp. 114-131 Bhattacharyya, K.G., Gupta, S.S., Adsorptive accumulation of cd(ii) co(ii) cu(ii) pb(ii) and ni(ii) from water on montmorillonite: Influence of acid activation (2007) J. Colloid Interface Sci., 310, pp. 411-424 Calero, M., Hernáinz, F., Blázquez, G., Martín-Lara, M.A., Tenorio, G., Biosorption kinetics of cd (ii), cr (iii) and pb (ii) in aqueous solutions by olive stone (2009) Braz. J. Chem. Eng., 26 (2), pp. 265-273 Della, V.P., Kuhn, I., Hotza, D., Characterization of rice husk ash for use as feedstock in the manufacture of silica refractories (2001) Quim. Nova, 24, pp. 778-782. , (In Portuguese Eren, E., Afsin, B., An investigation of cu2+ adsorption by raw and acid-activated bentonite: A combined potentiometric, thermodynamic, xrd, ir, dta study (2008) J. Hazard. Mater., 151, pp. 682-691 Futalan, C.M., Kan, C.-C., Dalida, M.L., Hsien, K.-J., Pascua, C., Wan, M.-W., Comparative and competitive adsorption of cooper, lead and nickel using chitosan immobilized on bentonite (2011) Carbohyd. Polym., 83, pp. 528-536 Galindo, L.S.G., De Almeida Neto, A.F., Silva, M.G.C., Vieira, M.G.A., Removal of cadmium(ii) and lead(ii) ions from aqueous phase on sodic bentonite (2013) Mater. Res., 16, pp. 515-527 Geankoplis, C.J., (1993) Transport Process and Unit Operations., , 3rd Ed. PTR Pretice Hall, USA Giraldo, L., Moreno-Piraján, J.C., Pb2+ adsorption from aqueous solutions on activated carbons obtained from lignocellulosic residues (2008) Braz. J. Chem. Eng., 25 (1), pp. 143-151 Gupta, V.K., Ali, I., Remove of lead and chromium from wastewater using bagasse fly ash-A sugar industry waste (2004) J. Colloid Interface Sci., 271, pp. 321-328 Ho, Y.S., Mckay, G., Wase, D.J., Foster, C.F., Study of the sorption of divalent metal ions on to peat (2000) Adsorpt. Sci. Technol., 18, pp. 639-650 Kamath, S.R., Proctor, A., Silica gel from rice hull ash: Preparation and characterization (1998) Cereal Chem., 75, pp. 484-487 Krishnani, K.K., Meng, X., Christodoulatos, C., Boddu, V.M., Bisorption mechanism of nine different heavy metals onto biomatrix from rice husk (2008) J. Hazard. Mater., 153, pp. 1222-1234 Krishnarao, R.V., Subrahmanyam, J., Kumar, T.J., Studies on the formation of black particles in rice husk silica ash (2001) J. Eur. Ceram. Soc., 21, pp. 99-104 Lagergren, S., Zur theorie der sogenannten adsorption geloster stoffe (1898) Kungliga Svenska Vetenskapsakademiens Handlingar, , (In Swedish Lv, Z., Yang, J., Wang, E., Yuan, H., Characterization of extracellular and substrate-bound cellulases from a mesophilic sugarcane bagassedegrading microbial community (2008) Process Biochem., 43, pp. 1467-1472 Moreno-Piraján, J.C., Garcia-Cuello, V.S., Giraldo, L., The removal and kinetic study of mn, fe, ni and cu ions from wastewater onto activated carbon from coconut shells (2011) Adsorption, 17, pp. 505-514 Mousavi, H.Z., Hosseynifar, A., Jahed, V., Dehghani, S.A.M., Removal of lead from aqueous solution using waste tire rubber ash as an adsorbent (2010) Braz. J. Chem. Eng., 27 (1), pp. 79-87 Naiya, T.K., Bhattacharya, A.K., Mandal, S., Das, S.K., The sorption of lead(ii) ions on rice husk ash (2009) J. Hazard. Mater., 163, pp. 1254-1264 Nakbanpote, W., Goodman, B.A., Thiravetyan, P., Cooper adsorption on rice husk derived materials studied by epr and ftir (2007) Colloid, Surface, A, 304, pp. 7-13 Nishikawa, E., Neto, A., De Almeida Neto, A.F., Vieira, M.G.A., Equilibrium and thermodynamic studies of zinc adsorption on expanded vermiculite (2012) Adsorption Sci. Technol., 30, pp. 759-772 Okolo, B., Park, C., Keane, M.A., Interaction of phenol and chlorophenols with activated carbon and synthetic zeolites in aqueous media (2000) J. Colloid Interface Sci., 226, pp. 308-317 Parab, H., Joshi, S., Shenoy, N., Lali, A., Sarma, U.S., Sudersanan, M., Determination of kinetic and equilibrium parameters of the batch adsorption of co(ii), cr(iii) and ni(ii) onto coir pith (2006) Process Biochem., 41, pp. 609-615 Puigdomenech, I., http://www.kemi.kth.se/medusa, HYDRA and MEDUSA Programs (Chemical Equilibrium Diagrams) Royal Institute of Technology, Sweden, software available at 2004Real, C., Alcalá, M.D., Criado, J.M., Preparation of sílica from rice husks (1996) J. Am. Ceram. Soc., 79, pp. 2012-2016 Ruthven, D.M., (1984) Principals of Adsorption and Adsorption Processes., , John Wiley & Sons, USA Senthil Kumar, P., Ramakrishnan, K., Dinesh Kirupha, S., Sivanesan, S., Thermodynamic and kinetic studies of cadmium adsorption from aqueous solution onto rice husk (2010) Braz. J. Chem. Eng., 27 (2), pp. 347-355 Silva, E.A., Cossich, E.S., Tavares, C.G., Cardozo Filho, L., Guirardello, R., Biosorption of binary mixtures of cr(iii) and cu(ii) ions by sargassum sp (2003) Braz. J. Chem. Eng., 20 (3), pp. 213-227 Srivastava, V.C., Mall, I.D., Mishra, I.M., Characterization of mesoporous rice husk ash (rha) and adsorption kinetics of metal ions from aqueous solution onto rha (2006) J. Hazard. Mater., 134, pp. 257-267 Tarley, C.R.T., Arruda, M.A.Z., Biosorption of heavy metals using rice milling by-products. Characterization and application for removal of metals from aqueous effluents (2004) Chemosphere, 54, pp. 987-995 Tarley, C.R.T., Ferreira, S.L.C., Arruda, M.A.Z., Use of modified rice husks as a natura solid adsorbent of trace metals: Characterization and development of an on-line preconcentration system for cadmium and lead determination by faas (2004) Microchem. J., 77, pp. 163-175 Teng, H., Wei, Y., Thermogravimetric studies on the kinectics of rice hull pyrolysis and the influence of water treatment (1998) Indian Eng. Chem. Res., 37, pp. 3806-3811 Torab-Mostaedi, M., Ghassabzadeh, H., Ghannadi-Maragheh, M., Ahmadi, S.J., Taheri, H., Removal of cadmium and nickel from aqueous solution using expanded perlite (2010) Braz. J. Chem. Eng., 27 (2), pp. 299-308 Vieira, M.G.A., Almeida Neto, A.F., Gimenes, M.L., Da Silva, M.G.C., Sorption kinects and equilibrium for the removal of nickel ions from aqueous phase on calcined bofe bentonite clay (2010) J. Hazard. Mater., 177, pp. 362-371 Vieira, M.G.A., Almeida Neto, A.F., Gimenes, M.L., Da Silva, M.G.C., Removal of nickel on bofe bentonite calcined clay in porous bed (2010) J. Hazard. Mater., 176, pp. 109-118 Vieira, M.G.A., Almeida Neto, A.F., Silva, M.G.C., Carneiro, C.N., Melo Filho, A.A., Characterization and use of in natura and calcined rice husks for biosorption of heavy metals ions from aqueous effluents (2012) Braz. J. Chem. Eng., 29, pp. 619-633 Vieira, M.G.A., Almeida Neto, A.F., Silva, M.G.C., Carneiro, C.N., Melo Filho, A.A., Influence of the system on adsorption of pb(ii) and cu(ii) by rice husks ash: Kinetic study (2011) Chem. Eng. Trans., 24, pp. 1213-1218 Vieira, M.G.A., Oisiovici, R.M., Gimenes, M.L., Silva, M.G.C., Biosorption of chromium (vi) using a sargassum sp packed-bed column (2008) Bioresour. Technol., 99, pp. 3094-3099 Vijayaranghavan, K., Jegan, J., Palanivelu, K., Velan, M., Biosorption of copper, cobalt and nickel by marine green alga ulva reticulata in a packed column (2005) Chemosphere, 60, pp. 416-426 Wahby, A., Abdelouahab-Reddam, Z., El Mail, R., Stitou, M., Silvestre-Albero, J., Sepúlveda-Escribano, A., Rodríguez-Reinoso, F., Mercury removal from aqueous solution by adsorption on activated carbons prepared from olive stones (2011) Adsorption, 17, pp. 603-609 Wang, S., Peng, Y., Natural zeolites as affective adsorbents in water and wastewater treatment (2010) Chem. Eng. J., 156, pp. 11-24 Weng, C.-H., Tsai, C.-Z., Chu, S.-H., Sharma, Y.C., Adsorption characteristics of copper(ii) onto spent activated clay (2007) Sep. Purif. Technol., 54, pp. 187-197 Ye, H., Zhu, Q., Du, D., Adsorptive removal of cd(ii) from aqueous solution using natural and modified rice husk (2010) Bioresour. Technol., 101, pp. 5175-5179 Yilmaz, M., Tay, T., Kivanc, M., Turk, H., Removal of corper(ii) ions from aqueous solution by a lactic acid bacterium (2010) Braz. J. Chem. Eng., 27 (2), pp. 309-314