Artículos de revistas
Thermochemical Properties Of Chelates Of Di-n-butyldithiocarbamate With Phosphorus-group Elements
Registro en:
The Journal Of Chemical Thermodynamics. , v. 21, n. 3, p. 283 - 291, 1989.
219614
10.1016/0021-9614(89)90018-9
2-s2.0-0008618541
Autor
Airoldi C.
De Souza A.G.
Institución
Resumen
The standard molar enthalpies of formation of crystalline tris(di-n-butyldithiocarbamato)e(III), (e = P, As, Sb, or Bi), determined at 298.15 K by solution-reaction calorimetry, are -(705.5 ± 7.3), -(443.1 ± 5.4), -(526.2 ± 2.5), and -(530.7 ± 5.5) kJ·mol-1, respectively. The enthalpies of sublimation: (136 ± 3), (128 ± 3), (179 ± 3), and (202 ± 3) kJ·mol-1, were estimated. From the enthalpies of formation of the gaseous complexes, the homolytic and hemolytic and heterolytic mean standard molar element-sulphur bond enthalpies were calculated. These values are correlated with element-sulphur bond distances, and a larger phosphorus-sulphur bond enthalpy reflects a better overlap of d orbitals in bonding formation. © 1989. 21 3 283 291 Magee, Hill, The Analytical Chemistry of Metal Dithiocarbamate Complexes (1985) Reviews in Analytical Chemistry, 8, p. 5 Coucouvanis, The Chemistry of the Dithioacid and 1,1-Dithiolate Complexes (1970) Progr. Inorg. Chem., 11, p. 233 Eisenberg, Structural Systematics of 1,1- and 1,2-Dithiolato Chelates (1970) Progr. Inorg. Chem., 12, p. 295 Coucouvanis, The Chemistry of the Dithioacid and 1, 1-Dithiolate Complexes, 1968–1977 (1979) Progr. Inorg. Chem., 26, p. 301 Bernard, Borel, (1969) Bull. Soc. Chem. Fr., 9, p. 3064 Hill, Magee, (1981) Rev. Inorg. Chem., 3, p. 141 Burkinshaw, Mortimer, (1983) Coord. Chem. Rev., 48, p. 101 Annuar, Hill, McIvor, Magee, (1974) Thermochim. Acta, 9, p. 143 Cavell, Hill, Magee, Standard enthalpy of formation of bis(diethyldithiocarbamato)nickel(II) at 298 K and the nickel?sulphur bond energy (1980) Journal of the Chemical Society, Dalton Transactions, p. 763 Cavell, Hill, Magee, Standard enthalpy of formation of bis(diethyldithiocarbamato)copper(II) at 298 K and the copper?sulphur bond energy (1980) Journal of the Chemical Society, Dalton Transactions, p. 1638 Airoldi, Zinc?sulphur bond enthalpy: its determination in the compound bis(diethyldithiocarbamato)zinc(II) (1985) Journal of the Chemical Society, Dalton Transactions, p. 369 Giera, Kakolowicz, (1987) Thermochim. Acta, 119, p. 311 Airoldi, Souza, Mean phosphorus? and arsenic?sulphur bond enthalpies in diethyldithiocarbamate chelate complexes (1987) Journal of the Chemical Society, Dalton Transactions, p. 2955 Souza, Airoldi, The thermochemistry of antimony(III) and bismuth(III) diethyldithiocarbamate complexes (1987) Thermochimica Acta, 130, p. 95 Cavell, Hill, Magee, (1979) J. Inorg. Nucl. Chem., 41, p. 1277 (1976) The Merck Index, p. 3081. , Merck and Co, Rahway, U.S.A Manoussakis, Karayannidis, (1970) Inorg. Nucl. Chem. Lett., 6, p. 71 Malatesta, (1939) Gazz. Chim. Ital., 69, p. 629 Oertel, Malz, Holtschmidt, Additionsreaktionen an Amide des Siliciums, Phosphors, Arsens und Schwefels (1964) Chemische Berichte, 97, p. 891 Whiton, Popoff, (1967) Chem. Abstr., 66, p. 1797r. , U.S. 3,281,234 Patent Jorge, Airoldi, Chagas, Thermochemistry of dichlorobis(triphenylphosphine oxide)-zinc(II), -cadmium(II), and -mercury(II) (1978) Journal of the Chemical Society, Dalton Transactions, p. 1102 Airoldi, Silva, Chagas, Heterocyclic nitrogen-containing electron-pair donor ligands: a thermochemical study of adducts with zinc, cadmium, and mercury chlorides (1986) Journal of the Chemical Society, Dalton Transactions, p. 1913 Kumar, Kaushik, Tris-Nethyl, m-tolyl)dithiocarbamato complexes of arsenic(III), antimony(III) and bismuth(III) (1980) Thermochimica Acta, 41, p. 19 Laila-Kantouri, Christofides, Manoussakis, (1984) J. Thermal Anal., 29, p. 279 Shankaranayana, Patel, Infrared absorption studies on some derivatives of xanthic, dithiocarbamic and trithiocarbonic acids (1965) Spectrochimica Acta, 21, p. 95 Manoussakis, Tsipis, (1973) J. Inorg. Nucl. Chem., 35, p. 743 Riekkola, Mass Spectrometric Study on Several Metal Dialkyldithiocarbamate Chelates. (1983) Acta Chemica Scandinavica, 37 A, p. 691 Ford, Edwards, (1969) Int. J. Mass Spectrom. Ion Phys., 2, p. 95 Finch, Hall, Standard enthalpies of formation and lattice energies of alkylammonium halides. Part 1. Propylamine hydrochlorides (1982) Journal of the Chemical Society, Dalton Transactions, p. 915 Ribeiro da Silva, Reis, Pilcher, (1987) J. Chem. Thermodynamics, 19, p. 837 Reid, Sherwood, (1968) The Properties of Gases and Liquids, , Second edn, McGraw-Hill, New York Janz, (1968) Thermodynamic Properties of Organic Compounds, , Revised edn., Academic Press, New York Sharma, Kumar, Khandpal, Chandra, Bhide, (1981) J. Inorg. Nucl. Chem., 43, p. 923 Petri, Tosi, Zannini, (1979) J. Mol. Struct., 53, p. 35 Yufit, Struchkov, Pudovick, Kibardina, Aleksandrova, Krairullin, Pudovick, (1980) Dokl. Phys. Chem., 255, p. 1058 Colapietro, Domenicano, Scaramuzza, Vaciago, (1968) J. Chem. Soc. Chem. Commun., p. 302 Cox, Pilcher, (1970) Thermochemistry of Organic and Organometallic Compounds, , Academic Press, New York McMillen, Goldem, Hydrocarbon Bond Dissociation Energies (1982) Annual Review of Physical Chemistry, 33, p. 493 Dasent, (1982) Inorganic Energetics—An Introduction, , Second edn., University Press, Cambridge Ruggiero, S. G. Unpublished resultsRibeiro da Silva, Pilcher, Irving, (1988) J. Chem. Thermodynamics, 20, p. 95