Artículos de revistas
Stereoselective total synthesis of some insect pheromones: (±)-serricornine and (±)-invictolide
Registro en:
Memórias do Instituto Oswaldo Cruz. Instituto Oswaldo Cruz, Ministério da Saúde, v. 86, p. 117-120, 1991.
0074-0276
S0074-02761991000600027
10.1590/S0074-02761991000600027
Autor
Pilli, R. A.
Murta, M. M.
Institución
Resumen
An efficient (12 steps, 12% overallyield) and stereoselective total synthesis of (±)-serricornine (1) the sex pheromone of the cigarette beetle (Lasioderma serricornine F) is described. The preparation of intermediate 5, which encompasses the proper relative configuration of three contiguous chiral centers of (±)-invictolide, (3), is discussed. 117 120