Adsorptive features of magnetic activated carbons prepared by a one-step process towards brilliant blue dye

dc.creatorNascimento, Victoria X.
dc.creatorSchnorr, Carlos Eduardo
dc.creatorLütke, Sabrina F.
dc.creatorDa Silva, Maria C. F.
dc.creatorM. Machado, Fernando
dc.creatorTHUE, Pascal Silas
dc.creatorLima, Eder Claudio
dc.creatorvieillard, julien
dc.creatorSilva Oliveira, Luis Felipe
dc.creatorDotto, Guilherme Luiz
dc.date2023-08-14T20:25:57Z
dc.date2023-08-14T20:25:57Z
dc.date2023-02-15
dc.date.accessioned2023-10-03T19:15:27Z
dc.date.available2023-10-03T19:15:27Z
dc.identifierNascimento, V.X.; Schnorr, C.; Lütke, S.F.; Da Silva, M.C.F.; Machado Machado, F.; Thue, P.S.; Lima, É.C.; Vieillard, J.; Silva, L.F.O.; Dotto, G.L. Adsorptive Features of Magnetic Activated Carbons Prepared by a One-Step Process towards Brilliant Blue Dye. Molecules 2023, 28, 1821. https://doi.org/ 10.3390/molecules28041821
dc.identifierhttps://hdl.handle.net/11323/10383
dc.identifier10.3390/molecules28041821
dc.identifier1420-3049
dc.identifierCorporación Universidad de la Costa
dc.identifierREDICUC - Repositorio CUC
dc.identifierhttps://repositorio.cuc.edu.co/
dc.identifier.urihttps://repositorioslatinoamericanos.uchile.cl/handle/2250/9169299
dc.descriptionWater pollution by dyes has been a major environmental problem to be tackled, and magnetic adsorbents appear as promising alternatives to solve it. Herein, magnetic activated carbons were prepared by the single−step method from Sapelli wood sawdust, properly characterized, and applied as adsorbents for brilliant blue dye removal. In particular, two magnetic activated carbons, MAC1105 and MAC111, were prepared using the proportion of biomass KOH of 1:1 and varying the proportion of NiCl2 of 0.5 and 1. The characterization results demonstrated that the different proportions of NiCl2 mainly influenced the textural characteristics of the adsorbents. An increase in the surface area from 260.0 to 331.5 m2 g−1 and in the total pore volume from 0.075 to 0.095 cm3 g−1 was observed with the weight ratio of NiCl2. Both adsorbents exhibit ferromagnetic properties and the presence of nanostructured Ni particles. The different properties of the materials influenced the adsorption kinetics and equilibrium of brilliant blue dye. MAC111 showed faster kinetics, reaching the equilibrium in around 10 min, while for MAC1105, it took 60 min for the equilibrium to be reached. In addition, based on the Sips isotherm, the maximum adsorption capacity was 98.12 mg g−1 for MAC111, while for MAC1105, it was 60.73 mg g−1. Furthermore, MAC111 presented the potential to be reused in more adsorption cycles than MAC1105, and the use of the adsorbents in the treatment of a simulated effluent exhibited high effectiveness, with removal efficiencies of up to 90%.
dc.format18 páginas
dc.formatapplication/pdf
dc.formatapplication/pdf
dc.languageeng
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)
dc.publisherSwitzerland
dc.relationMolecules
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dc.rightsAtribución 4.0 Internacional (CC BY 4.0)
dc.rightshttps://creativecommons.org/licenses/by/4.0/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.rightshttp://purl.org/coar/access_right/c_abf2
dc.sourcehttps://www.mdpi.com/1420-3049/28/4/1821
dc.subjectAdsorption
dc.subjectBrilliant blue
dc.subjectKinetic
dc.subjectSawdust
dc.subjectSimulated effluent
dc.titleAdsorptive features of magnetic activated carbons prepared by a one-step process towards brilliant blue dye
dc.typeArtículo de revista
dc.typehttp://purl.org/coar/resource_type/c_2df8fbb1
dc.typeText
dc.typeinfo:eu-repo/semantics/article
dc.typehttp://purl.org/redcol/resource_type/ART
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