Dba-free palladium intermediates of the Heck-Matsuda reaction

dc.contributorUniversidade Estadual Paulista (UNESP)
dc.creatorMacHado, Angelo H. L.
dc.creatorMilagre, Humberto M. S.
dc.creatorEberlin, Livia S.
dc.creatorSabino, Adão A.
dc.creatorCorreia, Carlos Roque D.
dc.creatorEberlin, Marcos N.
dc.date2014-05-27T11:29:32Z
dc.date2016-10-25T18:48:39Z
dc.date2014-05-27T11:29:32Z
dc.date2016-10-25T18:48:39Z
dc.date2013-05-28
dc.date.accessioned2017-04-06T02:24:28Z
dc.date.available2017-04-06T02:24:28Z
dc.identifierOrganic and Biomolecular Chemistry, v. 11, n. 20, p. 3277-3281, 2013.
dc.identifier1477-0520
dc.identifierhttp://hdl.handle.net/11449/75444
dc.identifierhttp://acervodigital.unesp.br/handle/11449/75444
dc.identifier10.1039/c3ob40142a
dc.identifierWOS:000318306400002
dc.identifier2-s2.0-84877257398
dc.identifierhttp://dx.doi.org/10.1039/c3ob40142a
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/896188
dc.descriptionThe dba-free Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(ii) during a Wacker type reaction and several dba-free arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested. © 2013 The Royal Society of Chemistry.
dc.languageeng
dc.relationOrganic and Biomolecular Chemistry
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCatalytic cycles
dc.subjectHeck-matsuda reactions
dc.subjectPalladium intermediates
dc.subjectPalladium species
dc.subjectTransient complexes
dc.subjectWacker-type reactions
dc.subjectChemistry
dc.subjectPositive ions
dc.subjectReaction intermediates
dc.titleDba-free palladium intermediates of the Heck-Matsuda reaction
dc.typeOtro


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