Síntesis y caracterización de nanoparticulas de TiFe2O4 mediante el método de Ablación Láser

dc.contributorRiascos Landazuri, Henry
dc.creatorGarzon Ovalle , Juan Diego
dc.date2022-02-18T14:01:49Z
dc.date2022-02-18T14:01:49Z
dc.date2021
dc.date.accessioned2022-09-23T20:59:10Z
dc.date.available2022-09-23T20:59:10Z
dc.identifierUniversidad Tecnológica de Pereira
dc.identifierRepositorio UTP
dc.identifierhttps://repositorio.utp.edu.co/home
dc.identifierhttps://hdl.handle.net/11059/13906
dc.identifier.urihttp://repositorioslatinoamericanos.uchile.cl/handle/2250/3523931
dc.descriptionEste trabajo de grado define dentro de su marco teorico la utilización de los materiales, los metodos y mecanismos de intervención. incluye una caracterización de nanomateriales y por utlimo se demuestra el trabajo experimental objeto del estudio. Incluye: imagenes de equipos y figuras de procedimientos.
dc.descriptionEn este proyecto se sintetizaron nano partículas (NPs), mediante el método de Ablación. Laser Pulsado (PLA) las cuales se obtuvieron desde un blanco solido de TiFeO en diferentes ambientes líquidos (Agua Des ionizada, Etanol y Metanol). Así mismo La morfología de las NPs se estudió mediante AFM (Microscopıa de Fuerza Atómica), Con Espectros copia Uv-vis se analizó las propiedades ´ ópticas, Se realizó con la estimación con del valor de la energía de Band Gap usando el método Tauc y con FTIR (Infrarrojos por Transformada de Fourier) se analizó su composición química. Las NPs de TiF e2O4 fueron sintetizadas en Agua Desionizada, Etanol y Metanol, usando un lente convergente de 10 cm de distancia focal, con el fin de condensar en un solo punto la intensidad del láser, que ser ´ a la zona de impacto en el blanco, para la producción de nanopartículas de T iF e2O4, bajo condición de temperatura ambiente (24°C ± 2°C). Se ablacionó con el láser de Neodymium-doped Yttrium aluminium Garnet (Nd:YAG) de la Universidad Tecnológica de Pereira, usando longitud de onda ´ λ= 1064 nm.
dc.descriptionIn this project, nanoparticles (NPs) were synthesized using the Pulsed Laser Ablation (PLA) method, which were obtained from a solid TiFeO target in different liquid environments (Deionized Water, Ethanol and Methanol). . Likewise, the morphology of the NPs was studied by AFM (Atomic Force Microscopy), with Uv-vis spectroscopy the optical properties were analyzed. Estimation of the Band Gap energy value using the Tauc method and its chemical composition was analyzed with FTIR (Fourier Transform Infrared). The T iF e2O4 NPs were synthesized in Deionized Water, Ethanol and Methanol, using a convergent lens with a focal length of 10 cm, in order to condense the laser intensity into a single point, which will be the zone impact on the target, for the production of T iF e2O4 nanoparticles, under a condition of room temperature (24 ° C ± 2 ° C). It was ablated with the Neodymium-doped Yttrium aluminum Garnet laser (Nd: YAG) from the Pereira Technological University, using wavelength = 1064 nm. The study of the chemical composition was carried out by FTIR using the Agilent Cary 630 FTIR Spectrometer equipment, which found compositions in 625 cm -1, in Deionized Water and in a variety of maxima such as 3382, 3282 and 1645 cm − 1 for 7:30 min and 1361, 1615, 1785, and 3230cm − 1 for 10:00 min of irradiation duration, UV-Vis characterization was performed, the results of which indicated a higher production. of NPs with absorption intensity in the UV region, which is characteristic of NPs with composition of T iO2, different absorption maxima, common in bimetallic NPs and surface plasma of the which their location is not clear due to the nature of these. It was carried out using a Meche-rey Nagel Nanocolor UV-Vis II spectrophotometer. Band gap values ??were estimated, whose values ??in deionized water as dispersion medium were close to the reference value mentioned 2.1 eV [9], unlike Ethanol and Methanolse. The morphology was carried out by Atomic Force Microscopy (AFM) using the Lex AFM version 5 C3000 controller, Nanosurf brand.
dc.descriptionPregrado
dc.descriptionIngeniero(a) Físico(a)
dc.descriptionIndice general Indice de figuras . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iv Indice de tablas . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v Agradecimientos vi Resumen vii 1. Preliminares 10 1.1. Introduccion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ´ 10 1.2. Planteamiento de pregunta o problema de investigacion y su justificaci ´ on´ en terminos de necesidades y pertinencia. . . . . . . . . . . . . . . . . . ´ 11 1.3. Objetivo general y espec´ıfico . . . . . . . . . . . . . . . . . . . . . . . . 14 1.3.1. Objetivo general . . . . . . . . . . . . . . . . . . . . . . . . . . 14 1.3.2. Objetivos espec´ıficos . . . . . . . . . . . . . . . . . . . . . . . . 14 I Teor´ıa General 15 2. Marco Teorico 16 ´ 2.1. Ferrita: Ferrita de Titanio (T iF e2O4) . . . . . . . . . . . . . . . . . . . . 16 2.2. S´ıntesis de nanoestructuras usando el metodo de Ablaci ´ on L ´ aser Pulsado ´ en L´ıquido (PLAL) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 2.3. Metodo de Ablaci ´ on L ´ aser P ´ ulsado en L ´ ´ıquido . . . . . . . . . . . . . . 20 2.3.1. Mecanismo de ablacion l ´ aser con pulsos en nanosegundos para la ´ produccion de Nanopart ´ ´ıculas Metalicas . . . . . . . . . . . . . . ´ 20 3. Caracterizacion de Nanomateriales 23 ´ 3.1. Espectroscop´ıa Ultravioleta-Visisble Uv-Vis . . . . . . . . . . . . . . . . 23 3.1.1. Espectroscop´ıa infrarroja de transfomada de Fourier . . . . . . . 25 3.1.2. Microscop´ıa de Fuerza Atomica . . . . . . . . . . . . . . . . . . ´ 26 II Trabajo Experimental 27 4. S´ıntesis de Nanopart´ıculas de T iF e2O4 28 4.1. Arreglo Optico . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ´ 28 4.2. Mecanismo de la ablacion l ´ aser en medios l ´ ´ıquidos . . . . . . . . . . . . 29 4.3. Equipos Utilizados para la caracterizacion de NPMs sintetizadas . . . . . ´ 30 ii 4.3.1. Uv-Vis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 30 4.3.2. FTIR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 III Resultados, analisis, discusiones y conclusiones 32 ´ 5. Resultados y Discusiones 33 5.1. Resultados de Caracterizacion de NPs de TiFeO . . . . . . . . . . . . . . ´ 33 5.1.1. Espectro de Absorbancia UV-Vis . . . . . . . . . . . . . . . . . 33 5.1.2. Espectroscop´ıa infrarroja de Transformada de Fourier . . . . . . . 45 5.1.3. Microscop´ıa de Fuerza Atomica (AFM) . . . . . . . . . . . . . . ´ 47 6. Discusion 49 ´ 7. Conclusiones 51 7.1. Conclusiones Uv-Vis . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51 7.2. Conclusiones de la Estimacion de Energ ´ ´ıa del Band Gap . . . . . . . . . 52 7.3. Conclusiones FTIR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 7.4. Conclusiones AFM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 Referencias 52
dc.format59 pag.
dc.formatapplication/pdf
dc.formatapplication/pdf
dc.languagespa
dc.publisherUniversidad Tecnológica de Pereira
dc.publisherFacultad de Ingenierías
dc.publisherPereira
dc.publisherIngeniería Física
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dc.rightsManifiesto (Manifestamos) en este documento la voluntad de autorizar a la Biblioteca Jorge Roa Martínez de la Universidad Tecnológica de Pereira la publicación en el Repositorio institucional (http://biblioteca.utp.edu.co), la versión electrónica de la OBRA titulada: ________________________________________________________________________________________________ ________________________________________________________________________________________________ ________________________________________________________________________________________________ La Universidad Tecnológica de Pereira, entidad académica sin ánimo de lucro, queda por lo tanto facultada para ejercer plenamente la autorización anteriormente descrita en su actividad ordinaria de investigación, docencia y publicación. La autorización otorgada se ajusta a lo que establece la Ley 23 de 1982. Con todo, en mi (nuestra) condición de autor (es) me (nos) reservo (reservamos) los derechos morales de la OBRA antes citada con arreglo al artículo 30 de
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dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacional (CC BY-NC-ND 4.0)
dc.rightshttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject620 - Ingeniería y operaciones afines::621 - Física aplicada
dc.subjectNanoparticulas
dc.subjectAblación
dc.subjectAnalisis espectral
dc.subjectAblación Láser
dc.subjectMicroscopía
dc.subjectTiFe2O4
dc.titleSíntesis y caracterización de nanoparticulas de TiFe2O4 mediante el método de Ablación Láser
dc.typeTrabajo de grado - Pregrado
dc.typehttp://purl.org/coar/resource_type/c_7a1f
dc.typehttp://purl.org/coar/version/c_ab4af688f83e57aa
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