Resistencia a la corrosión y al desgaste de películas delgadas de aceros inoxidables con y sin plata para aplicaciones biomédicas

dc.contributorOlaya Florez, Jhon Jairo
dc.contributorAperador Chaparro, William Arnulfo
dc.contributorGrupo de Investigación en Corrosión, Tribologia y Energía
dc.creatorEspaña Peña, Claudia Liliana
dc.date.accessioned2022-03-08T19:19:53Z
dc.date.available2022-03-08T19:19:53Z
dc.date.created2022-03-08T19:19:53Z
dc.date.issued2021-10-15
dc.identifierhttps://repositorio.unal.edu.co/handle/unal/81156
dc.identifierUniversidad Nacional de Colombia
dc.identifierRepositorio Institucional Universidad Nacional de Colombia
dc.identifierhttps://repositorio.unal.edu.co/
dc.description.abstractEn este trabajo de investigación se depositaron recubrimientos de acero inoxidable con y sin plata en forma de monocapas en atmósfera inerte y reactiva a partir de un blanco de acero inoxidable 316L por medio de la técnica Magnetrón Sputtering desbalanceado. Adicionalmente, se depositaron recubrimientos multicapas, alternando capas depositadas en atmósfera inerte y reactiva. Con el fin de evaluar el efecto que tiene la plata en las propiedades mecánicas y la corrosión de los recubrimientos, el blanco de acero inoxidable fue dopado con 1, 2, 3 y 4 insertos de plata. Los recubrimientos depositados fueron caracterizados química, estructural y mecánicamente, así como también su resistencia a la corrosión en solución de Ringer. Los recubrimientos exhibieron una estructura BCC cuando fueron depositados en atmósfera inerte, una estructura FCC en atmósfera reactiva y los recubrimientos multicapas presentaron ambas estructuras BCC y FCC. La composición química de los recubrimientos fue similar a la presentada por el blanco de acero 316L. El contenido de plata presentó una variación más significativa cuando el blanco fue dopado con 3 y 4 insertos de plata. El máximo valor se presentó en los recubrimientos de acero inoxidable dopados con 4 insertos de plata (13.1%at de Ag). La dureza de los recubrimientos se incrementó con el aumento del contenido de plata hasta alcanzar valores de 13GPa, mientras que la adherencia disminuyó. De igual forma, la resistencia al desgaste de los recubrimientos monocapas disminuyó con el incremento del contenido de plata. En cuanto a los recubrimientos multicapas, la resistencia al desgaste aumentó con el contenido de plata. La mejor respuesta frente a la corrosión se dio en los recubrimientos depositados sin plata, tanto para los recubrimientos monocapas como multicapas. El mejor comportamiento fue obtenido por esta última configuración. De acuerdo con lo anterior, los recubrimientos multicapas sin plata son una buena alternativa para ser empleados como materiales para aplicaciones biomédicas. (Texto tomado de la fuente).
dc.description.abstractIn this research work, stainless steel coatings with and without silver were deposited in the form of monolayers in an inert and reactive atmosphere from a 316L stainless steel target using the unbalanced Magnetron Sputtering technique. Additionally, multilayer coatings were deposited, alternating layers deposited in an inert and reactive atmosphere. In order to evaluate the effect that silver has on the mechanical and corrosion properties of the coatings the stainless steel target was doped with 1, 2, 3 and 4 silver inserts. The deposited coatings were characterized chemically, structurally, and mechanically, as well as their resistance to corrosion was evaluated by Ringer solution. The coatings exhibited a BCC structure when they were deposited in an inert atmosphere, an FCC structure when they were deposited in a reactive atmosphere, and the multilayer coatings exhibited both BCC and FCC structures. The chemical composition of the coatings was similar to 316L steel target. The silver content in the coatings presented a more significant variation when the target was doped with 3 and 4 silver inserts, where the maximum value was presented by the stainless steel coatings doped with 4 silver inserts (13.1% at Ag). The hardness of the coatings increased with the increase of the silver content reaching values up to 13 GPa, while the adhesion decreased, as well as the wear resistance of the monolayer coatings decreased with the increase of the silver content. On the other hand, the wear resistance on the multilayer coatings increased with addition of silver content. The best response to corrosion was presented by the coatings deposited without silver, for both monolayer and multilayer coatings, the behavior presented by this last configuration was the best compared to the other coatings configurations. According to the previous information, silver-free multilayer coatings are a good alternative to be used as materials for biomedical applications.
dc.languagespa
dc.publisherUniversidad Nacional de Colombia
dc.publisherBogotá - Ingeniería - Doctorado en Ingeniería - Ciencia y Tecnología de Materiales
dc.publisherDepartamento de Ingeniería Mecánica y Mecatrónica
dc.publisherFacultad de Ingeniería
dc.publisherUniversidad Nacional de Colombia - Sede Bogotá
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dc.rightsAtribución-NoComercial-SinDerivadas 4.0 Internacional
dc.rightshttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleResistencia a la corrosión y al desgaste de películas delgadas de aceros inoxidables con y sin plata para aplicaciones biomédicas
dc.typeTrabajo de grado - Doctorado


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